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In recent years, much research has been done on medical laser applications inside the human body, as they are minimally invasive and therefore have fewer side effects and are less expensive than conventional therapies. In order to bring the laser light into the human body, a glass fibre with a diffuser is needed. The goal of this master thesis is the characterization and production of fibre optic diffusers that can be used for the three therapeutic applications: photodynamic therapy, laser-induced thermotherapy and endovenous laser therapy. For this purpose the following goals have to be achieved:
- Optimization of the efficiency and homogeneity of internally structured diffusers
- Examine damage thresholds of the diffusers in the tissue using a crash test
- Achieving a better understanding of the decouple mechanism with a simulation
Using an ultra-short pulse laser, modifications could be introduced into the fibre in this way that the radiation profile is homogeneous and the decoupling efficiency is 68.3 %. It was discovered that the radiation profile depends on the wavelength. Attempts have been made to improve the decoupling efficiency by mirroring the distal end of the fibre. The mirror reflects the remaining light back into the fibre, so that it is also decoupled lateral on the modifications. Vapor-deposited aluminum with physical vapor deposition is a promising approach. However, the adhesion of the coating must be improved or the coating must be protected by a mechanical cover, otherwise it will flake off too quickly.
In a crash test, it was shown that the glass fibre diffusers can withstand 20 W laser power for 300 s without visible change. In an ex vivo test, the coagulation zone in the tissue was examined and it was showed that the diffusers radiate radially homogeneously. Using a ray trace simulation, the course of the light rays in the fibre was examined and the correlation of modification width and length with the decoupling efficiency was investigated. It was discovered that there are helical light rays in the fibre, which cannot be decoupled by modifications in the fibre centre.
A novel calorimetric technique for the analysis of gas-releasing endothermic dissociation reactions
(2020)
Real-time measurements of the differences in inhaled and exhaled, unlabeled and fully deuterated acetone concentration levels, at rest and during exercise, have been conducted using proton transfer reaction mass spectrometry. A novel approach to continuously differentiate between the inhaled and exhaled breath acetone concentration signals is used. This leads to unprecedented fine grained data of inhaled and exhaled concentrations. The experimental results obtained are compared with those predicted using a simple three compartment model that theoretically describes the influence of inhaled concentrations on exhaled breath concentrations for volatile organic compounds with high blood:air partition coefficients, and hence is appropriate for acetone. An agreement between the predicted and observed concentrations is obtained. Our results highlight that the influence of the upper airways cannot be neglected for volatiles with high blood:air partition coefficients, i.e. highly water soluble volatiles.
Optoelectronic system based on photonic integrated circuits to miniaturize spectral domain OCT
(2023)
We present a miniaturized optical coherence tomography (OCT) setup based on photonic integrated circuits (PIC) for the 850 nm range. We designed a 512-channel arrayed waveguide grating (AWG) on a PIC for spectral domain OCT (SD-OCT) that is co-integrated with PIN-photodiodes and analog-to-digital-converters on one single chip. This image sensor is combined with all the necessary electronics to act as a camera. It is integrated into a fiber-based OCT system, achieving a sensitivity of >80dB and various samples are imaged. This optoelectronic system will allow building small and cost-effective OCT systems to monitor retinal diseases.
X-ray micro tomography of three-dimensional embroidered current collectors for lithium-ion batteries
(2016)
Greater specific energy densities in lithium-ion batteries can be achieved by using three-dimensional (3D) porous current collectors, which allow for greater areal mass loadings of the electroactive material. In this paper, we present the use of embroidered current collectors for the preparation of thick, pouch-type Li-ion batteries. Experiments were performed on LiFePO 4 (LFP) water-based slurries using styrene-butadiene rubber (SBR) as binder and sodium carboxymethyl cellulose (CMC) as thickener, and formulations of different rheological characteristics were investigated. The electrochemical performance (cyclic voltammetry, rate capability) and morphological characteristics of the LFP half-pouch cells (X-ray micro computed tomography and scanning electron microscopy) were compared between the formulations. An optimum electrode formulation was identified, and a mechanism is proposed to explain differences between the formulations. With the optimum electrode formulation, 350 µm casted electrodes with high mechanical stability were achieved. Electrodes exhibited 4–6 times greater areal mass loadings (4–6 mAh cm −2 ) and 50% greater electroactive material weight than with foils. In tests of half- and full-pouch embroidered cells, a 50% capacity utilization at 1C-rate and 11% at 2C-rate were observed, with a full recovery at C/5-rate. The cycling stability was also maintained over 55 cycles.
Coupling is one of the most frequently mentioned metric in software systems. However, to measure logical coupling between microservices, runtime information is needed or the availability of service-log files to analyze the calls between services is required. This work presents our emerging results, in which we propose a metric to statically calculate logical coupling between microservices based on commits to versioning systems. We performed an initial validation of the proposed metric with a dataset containing 145 open-source microservices projects. The results illustrate how logical coupling affects every system and increases overtime. However, we did not find a correlation between the number of commits or the number of developers and the introduction of logical coupling. In future, we investigate why, how, and when logical coupling is introduced in a system.
Leadership, leader-follower relationship, and
subordinates’ behaviors during the Covid-19
pandemic
(2021)
The present research had compared how Uppsala and Bartlett & Ghoshal (B&G) models explain the internationalization process of the Brazilian pulp producer Fibria.
The Uppsala model describes the developments of capabilities that enable the firm to move towards higher commitments abroad. Despite its sine-qua-non dependence on foreign markets, it is unlikely that Fibria will internationalize its production to another country, given the country-specific advantages that the company has in Brazil. Nevertheless, Fibria set its structure abroad even when the direct exports would suffice to reach the markets without any foreign direct investment.
B&G deals with the aspects of the organizational structure and described the Transnational type as the evolution of the international firm. In their typology, Fibria was a Global and Ethnocentric type, but interestingly, elements of Transnational and Geocentric models were also observed in the company.
Both theories overlap or complement each other in many aspects. However, they could not explain the peculiarities of the internationalization of Fibria. One reason is the lack of country-related elements in these models.
Eventually, comparisons between theories such as those presented enable decision-makers to align the corporate strategy using suitable models, bearing in mind the limitations that each method entails.
Modern portable electronic devices have seen component heat load increasing, while the space available for heat dissipation has decreased. This requires the thermal management system to be optimized to attain the high performance heat sink. Heat sinks plays a major role for dissipating heat in electronic devices. Phase change material (PCM) is used to enhance the heat dissipation in heat sink. This paper reports the results of an experimental investigation of the performance of Pin fin heat sinks filled with phase change materials for thermal management of electronic devices. The experimental set ups are prepared with the graphical programming language with Lab VIEW (Laboratory Virtual Instruments for Engineering Workbench. Three different types of Pin fin Heat sink with and without PCM are investigated based on different operational timings and the temperature is acquired with the help of Data Acquisition Card (DAQ). The results indicated that the inclusion of the PCM could stabilize the temperature for a longer period and reduce the heating rates and peak temperatures of heat sink with increasing the number of fins can enhance the thermal performance of electronic devices.
Clathrate hydrates, or hydrates for short, are inclusion compounds in which water molecules form a hydrogen-bonded host lattice that accommodates the guest molecules. While vast amounts of hydrates are known to exist in seafloor sediments and in the permafrost on Earth, these occurrences might be dwarfed by the amounts of hydrates occurring in space and on celestial bodies. Since methane is the primary guest molecule in most of the natural occurrences on Earth, hydrates are considered a promising source of energy. Moreover, the ability of one volume of hydrate to store about 170 volumes of gas, make hydrates a promising functional material for various industrial applications. While the static properties of hydrates are reasonably well known, the dynamics of hydrate formation and decomposition are insufficiently understood. For instance, the stochastic period of hydrate nucleation, the memory effect, and the self-preservation phenomenon complicate the development of predictive models of hydrate dynamics. Additionally, the influence of meso- and macroscopic defects as well as the roles of mass and heat transport on different length scales remain to be clarified.
Due to its non-invasive and non-destructive nature and the high spatial resolution of approx. 1µm or even less, micro-computed X-ray attenuation tomography ( µCT ) seems to be the perfect method for the study of the evolving structures of forming or decomposing hydrates on the meso- and macroscopic length scale. However, for the naturally occurring hydrates of low atomic number guests the contrast between hydrate, ice, and liquid water is typically very weak because of similar X-ray attenuation coefficients. So far, good contrast was only restricted to synchrotron beamline experiments which utilize the phase information of monochromatic X-rays.
In this thesis it is shown that with the help of a newly developed sample cell, a contrast between the hydrate and the ice phase sufficiently good for the reliable segmentation of the materials can also be achieved in conventional tube-based µCT. An accurate pressure and temperature management, i.e., the added functionality of the cell, further allows for cross-correlation of structural and thermodynamic data. The capability of this µCT setup is demonstrated in a series of studies on the formation and decomposition of hydrates which yield new insights for the development of a novel route to hydrate synthesis. At last, this thesis points towards possibilities how better models of hydrate formation and decomposition can be developed with the aid of µCT and computer simulations.
Gas hydrates are usually synthesized by bringing together a pressurized gas and liquid or solid water. In both cases, the transport of gas or water to the hydrate growth site is hindered once an initial film of hydrate has grown at the water–gas interface. A seemingly forgotten gas-phase technique overcomes this problem by slowly depositing water vapor on a cold surface in the presence of the pressurized guest gas. Despite being used for the synthesis of low-formation-pressure hydrates, it has not yet been tested for hydrates of CO 2 and CH 4 . Moreover, the potential of the technique for the study of hydrate decomposition has not been recognized yet. We employ two advanced implementations of the condensation technique to form hydrates of CO 2 and CH 4 and demonstrate the applicability of the process for the study of hydrate decomposition and the phenomenon of self-preservation. Our results show that CO 2 and CH 4 hydrate samples deposited on graphite at 261–265 K are almost pure hydrates with an ice fraction of less than 8%. Rapid depressurization experiments with thin deposits (approx. 330 mm thickness) of CO 2 hydrate on an aluminum surface at 265 K yield identical dissociation curves when the deposition is done at identical pressure. However, hydrates deposited at 1 MPa almost completely withstand decomposition after rapid depressurization to 0.1 MPa, while samples deposited at 2 MPa decompose 7 times faster. Therefore, this synthesis technique is not only applicable for the study of hydrate decomposition but can also be used for the controlled deposition of a super-preserved hydrate.
Graphite substrates underwent two methods of creating doped silicon carbide films via carbothermal reduction; the first method being liquid-phase processing, or dip-coating, and the second gas-phase processing, otherwise referred to as the solid-vapour reaction. The dip-coating procedure resulted in flaky coatings, while the solid-vapour reaction resulted in polycrystalline films with columnar growth that displayed promising morphological and electrical properties. The films were tested on their performance as semiconductor diodes, and proved that carbothermal reduction in the gas phase is a promising technique for creating polycrystalline silicon carbide films for the application of light-emitting diodes.
The boom of information technology development created high demand for skilled labour force in IT occupations. IT professionals install, test, build, repair or maintain hardware and software and can do the job from any location in the world.
Demand for the workforce significantly outstrips the global supply. In a situation of staff shortage employers have to compete on local and global labour markets. The ability of a firm to attract and retain the best talent would become a source of its sustainable competitive advantage.
Aim of the study is to understand what influences perception of employment attractiveness by IT professionals the most. This study intends to expend the existing knowledge about employees´ needs and “psychological contract” concept.
The research was conducted with the participation of 4 IT and 4 HR English-speaking experts who live and work in Austria. In the study the grounded theory approach and the descriptive qualitative methods were applied.
The research findings explain which factors influence the decision of IT professionals to join, stay or leave an employer. The results are discussed in relation to talent attraction and retention practices of Austrian employers.
Signatures of the optical stark effect on entangled photon pairs from resonantly-pumped quantum dots
(2023)
Two-photon resonant excitation of the biexciton-exciton cascade in a quantum dot generates highly polarization-entangled photon pairs in a near-deterministic way. However, the ultimate level of achievable entanglement is still debated. Here, we observe the impact of the laser-induced ac-Stark effect on the quantum dot emission spectra and on entanglement. For increasing pulse-duration-to-lifetime ratios and pump powers, decreasing values of concurrence are recorded. Nonetheless, additional contributions are still required to fully account for the observed below-unity concurrence.
Increasing international competition and accelerated technological change characterize the environment in which companies must maintain and, if possible, expand their competitive advantage. In this context, the new, popular keyword innovation management is often mentioned. Many corporations propagate and use it for marketing purposes. As a result, the companies have to evaluate, develop and launch innovations increasingly faster, which poses great challenges for many and requires a high degree of adaptability.
This master thesis analyzes innovation management (IM) in the automotive industry and in other industries (material manufacturers, service providers, medicine, ...) depending on the number of employees and turnover. In addition, the maturity levels of the IMs and the innovation management systems (IMS) are examined. It also tries to determine which design or "building blocks" are necessary for a successful innovation management. Furthermore, factual and monetary guidelines by the management are evaluated. The thesis also aims to find out how the success of IM is measured. Therefore, guideline-based expert interviews were conducted with responsible people from the innovation departments and then systematically analyzed.
In the literature, expenses for innovations are often wrongly equated with the R&D rate. In this master thesis, it could be shown that this ratio is highest in the automotive industry. However, it does not correlate with the number of employees, turnover, maturity level, success or design of the IM. Furthermore, it could be shown that larger companies have a higher degree of maturity. The reason for this is that more people are usually involved in innovation and that a holistic understanding of innovation is better anchored in large corporations. When designing the IM or the roles of the innovation department, large companies use several different types. While the IM departments in small and medium-sized companies are usually incubators and accelerators, large companies also use corporate venture capital to support start-ups and develop new business models. In this thesis, the success of IM was determined by the number of innovations implemented in customer projects. It was found that, regardless of the size of the company, a higher degree of maturity of the IM and the accelerator role seem to have a positive influence.
Unfortunately, there are rarely concrete goals and targets set by the management although these, along with a holistic understanding of innovation in the company, are without doubt the most important part of a successful innovation management.
This thesis aims to support the product development process. Therefore, an approach is developed, implemented as a prototype and evaluated, for automated solution space exploration of formally predefined design automation tasks holding the product knowledge of engineers. For this reason, a classification of product development tasks related to the representation of the mathematical model is evaluated based on the parameters defined in this thesis. In a second step, the mathematical model should be solved. A Solver is identified able to handle the given problem class.
Due to the context of this work, System Modelling Language (SysML) is chosen for the product knowledge formalisation. In the next step the given SysML model has to be translated into an object-oriented model. This translation is implemented by extracting information of a ".xml"-file using the XML Metadata Interchanging (XMI) standard. The information contained in the file is structured using the Unified Modelling Language (UML) profile for SysML. Afterwards a mathematical model in MiniZinc language is generated. MiniZinc is a mathematical modelling language interpretable by many different Solvers. The generated mathematical model is classified related to the Variable Type and Linearity of the Constraints and Objective of the generated mathematical model. The output is stored in a ".txt"-file.
To evaluate the functionality of the prototype, time consumption of the different performed procedures is measured. This data shows that models containing Continuous Variables need a longer time to be classified and optimised. Another observation shows that the transformation into an object-oriented model and the translation of this model into a mathematical representation are dependent on the number of SysML model elements. Using MiniZinc resulted in the restriction that models which use non-linear functions and Boolean Expressions cannot be solved. This is because the implementation of non-linear Solvers at MiniZinc is still in the development phase. An investigation of the optimally of the results, provided by the Solvers, was left for further work.
Hot water heat pumps are well suited for demand side management, as the heat pump market faced a rapid growth in the past years with the trend to decentralized domestic hot water use. Sales were accelerated through wants and needs of energy conservation, energy efficiency, and less restrictive rules regarding Legionella. While in literature the model predictive control potential for heat pumps is commonly shown in simulations, the share of experimental studies is relatively low. To this day, experimental studies considering solely domestic hot water use are not available. In this paper, the realistic achievable model predictive control potential of a hot water heat pump is compared to the standard hysteresis control, to provide an experimental proof. We show for the first time, how state-of-the-art approaches (model predictive control, system identification, live state estimation, and demand prediction) can be transferred from electric hot water heaters to hot water heat pumps, combined, and implemented into a real-world hot water heat pump setup. The optimization approach, embedded in a realistic experimental setting, leads to a decrease in electric energy demand and cost per unit electricity by approximately 12% and 14%, respectively. Further, an increase in efficiency by approximately 13% has been achieved.
Flexibility estimation is the first step necessary to incorporate building energy systems into demand side management programs. We extend a known method for temporal flexibility estimation from literature to a real-world residential heat pump system, solely based on historical cloud data. The method proposed relies on robust simplifications and estimates employing process knowledge, energy balances and manufacturer's information. Resulting forced and delayed temporal flexibility, covering both domestic hot water and space heating demands as constraints, allows to derive a flexibility range for the heat pump system. The resulting temporal flexibility lay within the range of 24 minutes and 6 hours for forced and delayed flexibility, respectively. This range provides new insights into the system's behaviour and is the basis for estimating power and energy flexibility - the first step necessary to incorporate building energy systems into demand side management programs.
Activation of heat pump flexibilities is a viable solution to support balancing the grid via Demand Side Management measures and fulfill the need for flexibility options. Aggregators as interface between prosumers, distribution system operators and balance responsible parties face the challenge due to data privacy and technical restrictions to transform prosumer information into aggregated available flexibility to enable trading thereof. Thereby, literature lacks a generic, applicable and widely accepted flexibility estimation method for heat pumps,which incorporates reduced sensor and system information, system- and demand-dependent behaviour. In this paper, we adapt and extend a method from literature, by incorporating domain knowledge to overcome reduced sensor and system information. We apply data of five real-world heat pump systems, distinguish operation modes, estimate power and energy flexibility of each single heat pump system, proof transferability of the method, and aggregate the flexibilities available to showcase a small HP pool as a proof of concept.
Intelligence structure test
(2010)
The dynamics of self-adaptive multi-recombinant evolution strategies on the general ellipsoid model
(2014)
Nowadays, the area of customer management strives for omni-channel and state-of-the-art CRM concepts including Artificial Intelligence and the approach of Customer Experience. As a result, modern CRM solutions are essential tools for supporting customer processes in Marketing, Sales and Service. AI-driven CRM accelerates sales cycles, improves lead generation and qualification, and enables highly personalized marketing. The focus of this thesis is to present the basics of Customer Relationship Management, to show the latest Gartner insights about CRM and CX, and to demonstrate an AI Business Framework, which introduces AI use cases that are used as a basis for the expert interviews conducted in an international B2B company. AI will transform CX through a better understanding of customer behavior. The following research questions are answered in this thesis: In which AI use cases can Sales and CRM be improved? How can Customer Experience be improved with AI-driven CRM?
The presented master thesis of the study subject International Management and Leadership at the University of Applied Science Vorarlberg in Dornbirn handles the potential future influence of the EU Corporate Sustainability Due diligence on SMEs. First this thesis introduces the most important regulations that might come into place with this Due Diligence Act and gives a theoretical input when and how it will come into place, and also who it will affect directly and who will be affected indirectly. The empirical data resulted of several qualitative expert interviews and a following quantitative research. The expert interviews are split in two different groups, first the topic experts from institutions like chamber of commerce or chamber of labour and second experts from highly successful Austrian companies which are already handling the topic and the future challenges. Expected outcome of the qualitative interviews was a better view on the actual situation especially the impact on small and medium enterprises. On the basis of this results the quantitative survey was produced. In the quantitative survey the goal was to see, how much entrepreneurs and companies in the small and medium sector already are aware of the upcoming legal challenges throughout the supply chain. With all this collected data the practical outcome of this thesis is the Checklist, which helps entrepreneurs to find out if and how much they will be affected by the Act. And finally, the most important part is the Guideline, which introduces first risk assessment tools, that will help companies to prepare for future legislation and bring undoubtedly a certain advantage for the upcoming challenges.
Many test drives are carried out in the automotive environment. During these test drives many signals are recorded. The task of the test engineers is to find certain patterns (e.g. an emergency stop) in these long time series. Finding these interesting patterns is currently done with rule based processing. This procedure is very time consuming and requires a test engineer with expertise. In this thesis it is examined if the emerging field of machine learning can be used to support the engineers in this task. Active Learning, a subarea of machine learning, is used to train a classifier during the labeling process. Thereby it proposes similar windows to the already labeled ones. This saves the annotator time for searching or formulating rules for the problem. A data generator is worked out to replace the missing labeled data for tests. The custom performance measure “proportion of seen samples” is developed to make the success measurable. A modular software architecture is designed. With that, several combinations of Time Series Classification algorithms and query strategies are compared on artificial data. The results are verified on real datasets, which are open source available. The best performing, but computational intensive solution is an adapted RandOm Convolutional KErnel Transform (ROCKET). The custom query strategy “certainty sampling” shows the best results for highly imbalanced datasets.
Combining parallel pattern generation of electrohydrodynamic lithography with serial addressing
(2018)
For a given set of banks, how big can losses in bad economic or financial scenarios possibly get, and what are these bad scenarios? These are the two central questions of stress tests for banks and the banking system. Current stress tests select stress scenarios in a way which might leave aside many dangerous scenarios and thus create an illusion of safety; and which might consider highly implausible scenarios and thus trigger a false alarm. We show how to select scenarios systematically for a banking system in a context of multiple credit exposures. We demonstrate the application of our method in an example on the Spanish and Italian residential real estate exposures of European banks. Compared to the EBA 2016 stress test our method produces scenarios which are equally plausible as the EBA stress scenario but yield considerably worse system wide losses.
Towards a novel infrastructure for conducting high productive cloud-based scientific analytics
(2016)
Recently the use of microRNAs (miRNAs) as biomarkers for a multitude of diseases has gained substantial significance for clinical as well as point-of-care diagnostics. Amongst other challenges, however, it holds the central requirement that the concentration of a given miRNA must be evaluated within the context of other factors in order to unambiguously diagnose one specific disease. In terms of the development of diagnostic methods and devices, this implies an inevitable demand for multiplexing in order to be able to gauge the abundance of several components of interest in a patient’s sample in parallel. In this study, we design and implement different multiplexed versions of our electrochemical microfluidic biosensor by dividing its channel into subsections, creating four novel chip designs for the amplification-free and simultaneous quantification of up to eight miRNAs on the CRISPR-Biosensor X (‘X’ highlighting the multiplexing aspect of the device). We then use a one-step model assay followed by amperometric readout in combination with a 2-minute-stop-flow-protocol to explore the fluidic and mechanical characteristics and limitations of the different versions of the device. The sensor showing the best performance, is subsequently used for the Cas13a-powered proof-of-concept measurement of two miRNAs (miRNA-19b and miRNA-20a) from the miRNA-17∼92 cluster, which is dysregulated in the blood of pediatric medulloblastoma patients. Quantification of the latter, alongside simultaneous negative control measurements are accomplished on the same device. We thereby confirm the applicability of our platform to the challenge of amplification-free, parallel detection of multiple nucleic acids.
The Fast Average Current Mode control methodology is a novel method for the implementation of a current compensator in a switched-mode power supply. It does not require compensation against sub-harmonic instability and is inductor independent. In this work, the digital implementation of this topology is compared against an analog implementation using simulation. Additionally, a hardware prototype is created to validate the digital simulation's results. In a Simulink environment, parameters of the digital implementation, such as the digital-to-analog converter resolutions and the delay counter frequency are varied to research their impact on system performance. The simulations show that a digital current compensator has similar performance as an analog implementation when designed tailored to the application. When evaluating the whole control loop the digital system is inferior due to added delays caused by digital to analog conversion. By operating the Buck converter hardware implementation as a current source, the functionality of the current mode control implementation in a FPGA was proven. Voltage control cannot be validated due to hardware issues. Due to the successful simulation of the source code with a mixed signal model of the converter, it can be assumed that it is functional. Apart from performance, a digital implementation shows many benefits compared to an analog solution, such as configurability of control parameters and easy compensation of component variations and aging.
The spatial redistribution of Japanese direct investment in the United Kingdom between 1991 and 2010
(2013)
The goal of this paper is to design a low-loss 1 x 32 Y-branch optical splitter for optical transmission systems, using two different design tools employing Beam Propagation Method. As a first step, a conventional 1 x 32 Y-branch splitter was designed and simulated in two-dimensional environment of OptiBPM photonic tool. The simulated optical properties feature high loss, high asymmetric splitting ratio and a large size of the designed structure, too. In the second step of this work we propose an optimization of the conventional splitter design leading to suppression of the asymmetric splitting ratio to one-third of its initial value and to the improvement of the losses by nearly 2 dB. In addition, 50% size reduction of the designed structure was also achieved. This length-optimized low-loss splitter was then modelled in a three-dimensional environment of RSoft photonic tool and the simulated results confirm the strong improvement of the optical properties.
Design of low loss 1x64 y-branch splitter having symmetric splitting ratio and small footprint
(2014)
Learning together
(2019)