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Der Forschungsbericht gibt Antworten auf folgende Forschungsfrage: "Wie gestalten sich die interkulturellen Lebenswelten im Jahre 2021 im Orden der Steyler Missionare in St. Gabriel?" Das Erkenntnisinteresse dieser Studie ist, wie eine Ordensgemeinschaft in der heutigen Zeit funktioniert. Wie die veränderten gesellschaftlichen Werte, Normen und Regeln sich auswirken und wie sich ein normaler Alltag für ein Ordensmitglied gestaltet. Was es heißt zu missionieren und welche Erfahrungen Steyler Missionare hinsichtlich eines gelingenden interkulturellen Zusammenlebens haben, werden in dieser Studie beleuchtet. Die Recherchen zum Forschungsstand ergaben, dass es kaum Studien zum Ordensleben aus sozialwissenschaftlicher Sicht gibt. Die Lebenswelten der Ordensmitglieder werden mit Hilfe des lebensweltorientierten Ansatzes nach Thiersch und der Bedürfnistheorie nach Obrecht theoretisch fundiert. Das Sampling erfolgte mittels eines qualitativen Stichprobenplans. Die Datenerhebung erfolgte im Juli 2021. Die Auswertung erfolgte inhaltsanalytisch nach Mayring. Die Steyler Missionare können als weltoffene Ordensgemeinschaft betrachtet werden, deren Handeln wesentlich von den unterschiedlichen Missionserfahrungen geprägt ist. Ordensstrukturen unterscheiden sich deutlich von Strukturen der übrigen Gesellschaft. Diese Strukturen haben eine positive Wirkung auf die Ordensmitglieder. Diese, als auch eine sinnstiftende und erfüllende Tätigkeit sowie ein gewisses Maß an Freizeit ist anscheinend das Rezept für ein zufriedenes Leben. Die Mission hat für den Orden einen zentralen Stellenwert. Integration, Rassismus und Kolonialismus sind permanente Herausforderungen auch im Zusammenleben und werden aus verschiedenen Perspektiven diskutiert. In der Ordensgemeinschaft hat es viele Veränderungen gegeben, die Auswirkungen von diesen und der Umgang hiermit werden beschrieben sowie ein Blick in die Zukunft gewagt.
Real-time measurements of the differences in inhaled and exhaled, unlabeled and fully deuterated acetone concentration levels, at rest and during exercise, have been conducted using proton transfer reaction mass spectrometry. A novel approach to continuously differentiate between the inhaled and exhaled breath acetone concentration signals is used. This leads to unprecedented fine grained data of inhaled and exhaled concentrations. The experimental results obtained are compared with those predicted using a simple three compartment model that theoretically describes the influence of inhaled concentrations on exhaled breath concentrations for volatile organic compounds with high blood:air partition coefficients, and hence is appropriate for acetone. An agreement between the predicted and observed concentrations is obtained. Our results highlight that the influence of the upper airways cannot be neglected for volatiles with high blood:air partition coefficients, i.e. highly water soluble volatiles.
Optoelectronic system based on photonic integrated circuits to miniaturize spectral domain OCT
(2023)
We present a miniaturized optical coherence tomography (OCT) setup based on photonic integrated circuits (PIC) for the 850 nm range. We designed a 512-channel arrayed waveguide grating (AWG) on a PIC for spectral domain OCT (SD-OCT) that is co-integrated with PIN-photodiodes and analog-to-digital-converters on one single chip. This image sensor is combined with all the necessary electronics to act as a camera. It is integrated into a fiber-based OCT system, achieving a sensitivity of >80dB and various samples are imaged. This optoelectronic system will allow building small and cost-effective OCT systems to monitor retinal diseases.
X-ray micro tomography of three-dimensional embroidered current collectors for lithium-ion batteries
(2016)
Greater specific energy densities in lithium-ion batteries can be achieved by using three-dimensional (3D) porous current collectors, which allow for greater areal mass loadings of the electroactive material. In this paper, we present the use of embroidered current collectors for the preparation of thick, pouch-type Li-ion batteries. Experiments were performed on LiFePO 4 (LFP) water-based slurries using styrene-butadiene rubber (SBR) as binder and sodium carboxymethyl cellulose (CMC) as thickener, and formulations of different rheological characteristics were investigated. The electrochemical performance (cyclic voltammetry, rate capability) and morphological characteristics of the LFP half-pouch cells (X-ray micro computed tomography and scanning electron microscopy) were compared between the formulations. An optimum electrode formulation was identified, and a mechanism is proposed to explain differences between the formulations. With the optimum electrode formulation, 350 µm casted electrodes with high mechanical stability were achieved. Electrodes exhibited 4–6 times greater areal mass loadings (4–6 mAh cm −2 ) and 50% greater electroactive material weight than with foils. In tests of half- and full-pouch embroidered cells, a 50% capacity utilization at 1C-rate and 11% at 2C-rate were observed, with a full recovery at C/5-rate. The cycling stability was also maintained over 55 cycles.
net culture lab Katalog
(2010)
Coupling is one of the most frequently mentioned metric in software systems. However, to measure logical coupling between microservices, runtime information is needed or the availability of service-log files to analyze the calls between services is required. This work presents our emerging results, in which we propose a metric to statically calculate logical coupling between microservices based on commits to versioning systems. We performed an initial validation of the proposed metric with a dataset containing 145 open-source microservices projects. The results illustrate how logical coupling affects every system and increases overtime. However, we did not find a correlation between the number of commits or the number of developers and the introduction of logical coupling. In future, we investigate why, how, and when logical coupling is introduced in a system.
Der Presse kam zu Beginn des 20. Jahrhunderts eine außerordentlich wichtige Rolle in der Auseinandersetzung zwischen den politischen Lagern, Sozialdemokratie, Deutschnationalismus und Christlich-Soziale Bewegung zu. Jedes der drei Lager hatte ihm mal mehr mal weniger zugeordnete Zeitungen, die reichsweit erschienen oder kleinere Lokal- und Provinzblätter waren. Der Pius-Verein zur Unterstützung der katholischen Presse engagierte sich in dieser Auseinandersetzung für die Sache des politischen Katholizismus. Seine Methoden bestanden in der politischen Agitation und im Sammeln von Spenden für katholische Zeitungen. Im Kronland Tirol war einer der aktivsten Ableger des Pius-Vereins tätig, mit Ortsgruppen in fast jeder Gemeinde.
Trotz der Relevanz von Partizipationsprozessen in Unternehmen und deren belegte Auswirkungen zeigt sich ein deutliches Ungleichgewicht zwischen der aufgezeigten Bedeutung von Beteiligungsprozessen und dem gleichzeitig geringen Umsetzungsstand in Betrieben. Deshalb soll geprüft werden, inwiefern sich die Erwartungen jüngerer Mitarbeiter:innen mit ihrer erlebten Arbeitsrealität decken. Dazu wurden 459 Personen (59,5% Frauen) im Alter zwischen 16 und 35 Jahren zu allgemeinen Partizipationsmöglichkeiten und zu flexiblen Arbeitsbedingungen befragt. Es zeigen sich signifikante Unterschiede in beiden Teilbereichen der Partizipation zwischen den Erwartungen der Arbeitnehmer:innen und deren erlebter Realität in den Unternehmen. Über Angleichung der betrieblichen Realitäten der Partizipation könnten Unternehmen und Mitarbeiter:innen auf verschiedenen Ebenen gewinnen.
Clathrate hydrates, or hydrates for short, are inclusion compounds in which water molecules form a hydrogen-bonded host lattice that accommodates the guest molecules. While vast amounts of hydrates are known to exist in seafloor sediments and in the permafrost on Earth, these occurrences might be dwarfed by the amounts of hydrates occurring in space and on celestial bodies. Since methane is the primary guest molecule in most of the natural occurrences on Earth, hydrates are considered a promising source of energy. Moreover, the ability of one volume of hydrate to store about 170 volumes of gas, make hydrates a promising functional material for various industrial applications. While the static properties of hydrates are reasonably well known, the dynamics of hydrate formation and decomposition are insufficiently understood. For instance, the stochastic period of hydrate nucleation, the memory effect, and the self-preservation phenomenon complicate the development of predictive models of hydrate dynamics. Additionally, the influence of meso- and macroscopic defects as well as the roles of mass and heat transport on different length scales remain to be clarified.
Due to its non-invasive and non-destructive nature and the high spatial resolution of approx. 1µm or even less, micro-computed X-ray attenuation tomography ( µCT ) seems to be the perfect method for the study of the evolving structures of forming or decomposing hydrates on the meso- and macroscopic length scale. However, for the naturally occurring hydrates of low atomic number guests the contrast between hydrate, ice, and liquid water is typically very weak because of similar X-ray attenuation coefficients. So far, good contrast was only restricted to synchrotron beamline experiments which utilize the phase information of monochromatic X-rays.
In this thesis it is shown that with the help of a newly developed sample cell, a contrast between the hydrate and the ice phase sufficiently good for the reliable segmentation of the materials can also be achieved in conventional tube-based µCT. An accurate pressure and temperature management, i.e., the added functionality of the cell, further allows for cross-correlation of structural and thermodynamic data. The capability of this µCT setup is demonstrated in a series of studies on the formation and decomposition of hydrates which yield new insights for the development of a novel route to hydrate synthesis. At last, this thesis points towards possibilities how better models of hydrate formation and decomposition can be developed with the aid of µCT and computer simulations.
Gas hydrates are usually synthesized by bringing together a pressurized gas and liquid or solid water. In both cases, the transport of gas or water to the hydrate growth site is hindered once an initial film of hydrate has grown at the water–gas interface. A seemingly forgotten gas-phase technique overcomes this problem by slowly depositing water vapor on a cold surface in the presence of the pressurized guest gas. Despite being used for the synthesis of low-formation-pressure hydrates, it has not yet been tested for hydrates of CO 2 and CH 4 . Moreover, the potential of the technique for the study of hydrate decomposition has not been recognized yet. We employ two advanced implementations of the condensation technique to form hydrates of CO 2 and CH 4 and demonstrate the applicability of the process for the study of hydrate decomposition and the phenomenon of self-preservation. Our results show that CO 2 and CH 4 hydrate samples deposited on graphite at 261–265 K are almost pure hydrates with an ice fraction of less than 8%. Rapid depressurization experiments with thin deposits (approx. 330 mm thickness) of CO 2 hydrate on an aluminum surface at 265 K yield identical dissociation curves when the deposition is done at identical pressure. However, hydrates deposited at 1 MPa almost completely withstand decomposition after rapid depressurization to 0.1 MPa, while samples deposited at 2 MPa decompose 7 times faster. Therefore, this synthesis technique is not only applicable for the study of hydrate decomposition but can also be used for the controlled deposition of a super-preserved hydrate.
Hot water heat pumps are well suited for demand side management, as the heat pump market faced a rapid growth in the past years with the trend to decentralized domestic hot water use. Sales were accelerated through wants and needs of energy conservation, energy efficiency, and less restrictive rules regarding Legionella. While in literature the model predictive control potential for heat pumps is commonly shown in simulations, the share of experimental studies is relatively low. To this day, experimental studies considering solely domestic hot water use are not available. In this paper, the realistic achievable model predictive control potential of a hot water heat pump is compared to the standard hysteresis control, to provide an experimental proof. We show for the first time, how state-of-the-art approaches (model predictive control, system identification, live state estimation, and demand prediction) can be transferred from electric hot water heaters to hot water heat pumps, combined, and implemented into a real-world hot water heat pump setup. The optimization approach, embedded in a realistic experimental setting, leads to a decrease in electric energy demand and cost per unit electricity by approximately 12% and 14%, respectively. Further, an increase in efficiency by approximately 13% has been achieved.
Activation of heat pump flexibilities is a viable solution to support balancing the grid via Demand Side Management measures and fulfill the need for flexibility options. Aggregators as interface between prosumers, distribution system operators and balance responsible parties face the challenge due to data privacy and technical restrictions to transform prosumer information into aggregated available flexibility to enable trading thereof. Thereby, literature lacks a generic, applicable and widely accepted flexibility estimation method for heat pumps,which incorporates reduced sensor and system information, system- and demand-dependent behaviour. In this paper, we adapt and extend a method from literature, by incorporating domain knowledge to overcome reduced sensor and system information. We apply data of five real-world heat pump systems, distinguish operation modes, estimate power and energy flexibility of each single heat pump system, proof transferability of the method, and aggregate the flexibilities available to showcase a small HP pool as a proof of concept.