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Der Befeuchtungs-Entfeuchtungs-Prozess (HDH) wird zur Meerwasserentsalzung eingesetzt und bietet Vorteile wie die Nutzung von Wärme auf einem geringen Temperaturniveau sowie die Realisierbarkeit dezentraler Anlagen. Bei diesem Prozess wird Luft im Kontakt mit warmem Salzwasser im Optimalfall bis zur Sättigung befeuchtet. Die feuchte Luft wird anschließend abgekühlt, um das in ihr befindliche Wasser wieder zu kondensieren. Obwohl der HDH-Prozess bereits mehrfach Gegenstand der Forschung war, besitzt die Effizienz des Prozesses nach wie vor ein hohes Steigerungspotential. Das Ziel dieser Masterarbeit besteht in der Konzeption und der Realisierung eines Versuchsaufbaus zur Analyse der Befeuchtung von Luft in Wasser. Dabei soll der Untersuchungsgegenstand zukünftiger Versuche die Befeuchtereinheit sein, die ein hohes Potential hinsichtlich der Effizienzsteigerung von HDH-Systemen bietet. In neueren Publikationen wurden zum Einsatz in HDH-Systemen Blasensäulenbefeuchter als eine bessere Alternative zu Festbettbefeuchtern oder Sprühtürmen vorgeschlagen, weswegen die Befeuchtung in solchen Aggregaten näher untersucht werden muss. Das Hauptziel dieser Masterarbeit ist ein Versuchsaufbau, der die Möglichkeit bietet, die Parameter, die die Befeuchtung von Luft in einer Blasensäule maßgeblich beeinflussen, mit einer ausreichenden Genauigkeit zu messen, um aus diesen Messungen semiempirische Korrelationen ableiten zu können. Die die Befeuchtung von Luft maßgeblich beeinflussenden Parameter sind die Wassertemperatur, der Füllstand im Befeuchter, die Luftgeschwindigkeit sowie die Blasengröße.
Zum aktuellen Stand ist ein HDH-System, bestehend aus einem Blasensäulenbefeuchter, einem Querstromwärmetauscher sowie einer Dosierpumpe errichtet. Mit diesem System können wissenschaftlich notwendige empirische Zusammenhänge zwischen den die Befeuchtung beeinflussenden Parametern und der Befeuchtung von Luft aus Versuchen abgeleitet werden. Die im Versuchsaufbau verbaute Messtechnik wurde derart ausgewählt, dass deren Einfluss auf das System so gering wie möglich gehalten werden kann.
Mit dem Versuchsaufbau ist es darüber hinaus möglich, invasive Messmethoden mit nicht invasiven Messmethoden direkt zu vergleichen. Um eine für die Messungen optimale Befeuchtergeometrie zu finden, sind zwei Blasensäulenbefeuchtereinheiten aufgebaut, davon eine mit planarem und eine mit zylindrischem Querschnitt. So ist es möglich, im Direktvergleich die Vor- und Nachteile der Querschnittsanordnungen nachzuweisen. Die Komponenten der beiden HDH-Systeme wurden anhand von wissenschaftlich akzeptierten Modellen bezüglich der dazugehörigen Wärmeübertragungsraten, der Wärmeverluste und der Druckverluste ausgelegt.
Eine Modellierung des Stoffübergangs in der Blasensäule ist durchgeführt. Anhand dieser Modellierung konnte der Stoffübergangskoeffizient in der Grenzschicht zwischen Luftblase und Flüssigkeitssäule ermittelt werden. Anhand einer Massenbilanz konnte über den Stoffübergangskoeffizienten die Austrittswasserbeladung der feuchten Luft modelliert werden.
Die Funktionalität des Versuchsaufbaus ist gegeben. Messungen des Gasgehalts zeigen eine sehr gute Übereinstimmung mit wissenschaftlich anerkannten Korrelationen zum Gasgehalt. Die optische Zugänglichkeit des Versuchsaufbaus ist evaluiert und lässt die Tendenz ableiten, dass sich ein planarer Befeuchterquerschnitt in Verbindung mit Fotoaufnahmen von den durchgeführten Varianten am besten zur digitalen Bildanalyse eignet.
Aus den Experimenten, die am realisierten Versuchsaufbau durchgeführt werden, kann sich eine allgemeingültige Auslegungsgrundlage für Versuchsaufbauten ergeben, mit denen Messungen der Befeuchtung von Luft in Blasensäulenbefeuchtern durchgeführt werden sollen.
The humidification-dehumidification process (HDH) for desalination is a promising technology to address water scarcity issues in rural regions. However, a low humidifier efficiency is a weakness of the process. Bubble column humidifiers (BCH) are promising for HDH, as they provide enhanced heat and mass transfer and have low maintenance requirements. Previous studies of HDH-systems with BCHs draw different conclusions regarding the impact of superficial air velocity and liquid height on the humidification. Furthermore, the impact of flow characteristics has never been investigated systematically at all. In this study, an optimized BCH test setup that allows for optical analysis of the humidifier is used and evaluated. Our test setup is validated, since the influence of water temperature on the humidification, which is exponential, is reproduced. Measurements with seawater show that the normalised system productivity is increased by about 56 % with an increase in superficial air velocity from 0.5 to 5 cm/s. Furthermore, the system productivity is increased by around 29 % with an increase in liquid height from 60 to 378 mm. While the impact of superficial air velocity can be traced back to temperature changes at the humidifier and dehumidifier outlets, the impact of liquid height is shown to be caused by a smaller heat loss surface in the humidifier with an increase in liquid height. For the impact of sieve plate orifice diameter, a clear influence on the humidification is not apparent, this parameter needs to be investigated further. Finally, our new test setup allows for analysing the humidification of air (1) in a systematic way, (2) in relevant measurement ranges and (3) in comparison with optical analyses of the flow characteristics.
Greater specific energy densities in lithium-ion batteries can be achieved by using three-dimensional (3D) porous current collectors, which allow for greater areal mass loadings of the electroactive material. In this paper, we present the use of embroidered current collectors for the preparation of thick, pouch-type Li-ion batteries. Experiments were performed on LiFePO 4 (LFP) water-based slurries using styrene-butadiene rubber (SBR) as binder and sodium carboxymethyl cellulose (CMC) as thickener, and formulations of different rheological characteristics were investigated. The electrochemical performance (cyclic voltammetry, rate capability) and morphological characteristics of the LFP half-pouch cells (X-ray micro computed tomography and scanning electron microscopy) were compared between the formulations. An optimum electrode formulation was identified, and a mechanism is proposed to explain differences between the formulations. With the optimum electrode formulation, 350 µm casted electrodes with high mechanical stability were achieved. Electrodes exhibited 4–6 times greater areal mass loadings (4–6 mAh cm −2 ) and 50% greater electroactive material weight than with foils. In tests of half- and full-pouch embroidered cells, a 50% capacity utilization at 1C-rate and 11% at 2C-rate were observed, with a full recovery at C/5-rate. The cycling stability was also maintained over 55 cycles.
Gas hydrates are usually synthesized by bringing together a pressurized gas and liquid or solid water. In both cases, the transport of gas or water to the hydrate growth site is hindered once an initial film of hydrate has grown at the water–gas interface. A seemingly forgotten gas-phase technique overcomes this problem by slowly depositing water vapor on a cold surface in the presence of the pressurized guest gas. Despite being used for the synthesis of low-formation-pressure hydrates, it has not yet been tested for hydrates of CO 2 and CH 4 . Moreover, the potential of the technique for the study of hydrate decomposition has not been recognized yet. We employ two advanced implementations of the condensation technique to form hydrates of CO 2 and CH 4 and demonstrate the applicability of the process for the study of hydrate decomposition and the phenomenon of self-preservation. Our results show that CO 2 and CH 4 hydrate samples deposited on graphite at 261–265 K are almost pure hydrates with an ice fraction of less than 8%. Rapid depressurization experiments with thin deposits (approx. 330 mm thickness) of CO 2 hydrate on an aluminum surface at 265 K yield identical dissociation curves when the deposition is done at identical pressure. However, hydrates deposited at 1 MPa almost completely withstand decomposition after rapid depressurization to 0.1 MPa, while samples deposited at 2 MPa decompose 7 times faster. Therefore, this synthesis technique is not only applicable for the study of hydrate decomposition but can also be used for the controlled deposition of a super-preserved hydrate.
Clathrate hydrates, or hydrates for short, are inclusion compounds in which water molecules form a hydrogen-bonded host lattice that accommodates the guest molecules. While vast amounts of hydrates are known to exist in seafloor sediments and in the permafrost on Earth, these occurrences might be dwarfed by the amounts of hydrates occurring in space and on celestial bodies. Since methane is the primary guest molecule in most of the natural occurrences on Earth, hydrates are considered a promising source of energy. Moreover, the ability of one volume of hydrate to store about 170 volumes of gas, make hydrates a promising functional material for various industrial applications. While the static properties of hydrates are reasonably well known, the dynamics of hydrate formation and decomposition are insufficiently understood. For instance, the stochastic period of hydrate nucleation, the memory effect, and the self-preservation phenomenon complicate the development of predictive models of hydrate dynamics. Additionally, the influence of meso- and macroscopic defects as well as the roles of mass and heat transport on different length scales remain to be clarified.
Due to its non-invasive and non-destructive nature and the high spatial resolution of approx. 1µm or even less, micro-computed X-ray attenuation tomography ( µCT ) seems to be the perfect method for the study of the evolving structures of forming or decomposing hydrates on the meso- and macroscopic length scale. However, for the naturally occurring hydrates of low atomic number guests the contrast between hydrate, ice, and liquid water is typically very weak because of similar X-ray attenuation coefficients. So far, good contrast was only restricted to synchrotron beamline experiments which utilize the phase information of monochromatic X-rays.
In this thesis it is shown that with the help of a newly developed sample cell, a contrast between the hydrate and the ice phase sufficiently good for the reliable segmentation of the materials can also be achieved in conventional tube-based µCT. An accurate pressure and temperature management, i.e., the added functionality of the cell, further allows for cross-correlation of structural and thermodynamic data. The capability of this µCT setup is demonstrated in a series of studies on the formation and decomposition of hydrates which yield new insights for the development of a novel route to hydrate synthesis. At last, this thesis points towards possibilities how better models of hydrate formation and decomposition can be developed with the aid of µCT and computer simulations.
Verbraucherseitige Laststeuerung (Demand Side Management – DSM) wird als ein möglicher Ansatz betrachtet, um die Auswirkungen des Ausbaus von fluktuierenden Erneuerbaren im Stromnetz auszugleichen. Sollen viele verteilte Energiesysteme damit angesprochen werden, stellen zentralistische Ansätze dabei hohe Anforderungen an die Kommunikationsinfrastruktur. Als Alternative wird vielfach eine autonome Laststeuerung (ADSM) mit anreizbasierter Optimierung direkt auf dem Verbrauchergerät betrachtet. Dabei kann die Anreizfunktion mittels unidirektionaler Kommunikation übertragen werden.
Am Forschungszentrum Energie der Fachhochschule Vorarlberg wurden in den letzten Jahren Algorithmen und Prototypen für den Einsatz von ADSM auf verschiedensten verteilten Energiespeichern im elektrischen Stromnetz entwickelt. Dabei werden sowohl thermische Energiespeicher (z. B. Haushalts-Warmwasserspeicher) als auch elektrochemische Speicher (z. B. Batteriespeichersysteme oder Elektroautos) betrachtet. Außerdem werden die Auswirkungen solcher Systeme auf das elektrische Verteilnetz untersucht. Dieser Artikel gibt einen Überblick über die entwickelten Methoden und Ergebnisse aus diesem Forschungsfeld mit dem Ziel, ein weitreichendes Verständnis für die Chancen und Grenzen des ADSM zu schaffen.
In the regime of incentive-based autonomous demand response, time dependent prices are typically used to serve as signals from a system operator to consumers. However, this approach has been shown to be problematic from various perspectives. We clarify these shortcomings in a geometric way and thereby motivate the use of power signals instead of price signals. The main contribution of this paper consists of demonstrating in a standard setting that power tracking signals can control flexibilities more efficiently than real-time price signals. For comparison by simulation, German renewable energy production and German standard load profiles are used for daily production and demand profiles, respectively. As for flexibility, an energy storage system with realistic efficiencies is considered. Most critically, the new approach is able to induce consumptions on the demand side that real-time pricing is unable to induce. Moreover, the pricing approach is outperformed with regards to imbalance energy, peak consumption, storage variation, and storage losses without the need for additional communication or computation efforts. It is further shown that the advantages of the optimal power tracking approach compared to the pricing approach increase with the extent of the flexibility. The results indicate that autonomous flexibility control by optimal power tracking is able to integrate renewable energy production efficiently, has additional benefits, and the potential for enhancements. The latter include data uncertainties, systems of flexibilities, and economic implementation.
If left uncontrolled, electric vehicle charging poses severe challenges to distribution grid operation. Resulting issues are expected to be mitigated by charging control. In particular, voltage-based charging control, by relying only on the local measurements of voltage at the point of connection, provides an autonomous communication-free solution. The controller, attached to the charging equipment, compares the measured voltage to a reference voltage and adapts the charging power using a droop control characteristic. We present a systematic study of the voltage-based droop control method for electric vehicles to establish the usability of the method for all the currently available residential electric vehicle charging possibilities considering a wide range of electric vehicle penetrations. Voltage limits are evaluated according to the international standard EN50160, using long-term load flow simulations based on a real distribution grid topology and real load profiles. The results achieved show that the voltage-based droop controller is able to mitigate the under voltage problems completely in distribution grids in cases either deploying low charging power levels or exhibiting low penetration rates. For high charging rates and high penetrations, the control mechanism improves the overall voltage profile, but it does not remedy the under voltage problems completely. The evaluation also shows the controller’s ability to reduce the peak power at the transformer and indicates the impact it has on users due to the reduction in the average charging rates. The outcomes of the paper provide the distribution grid operators an insight on the voltage-based droop control mechanism for the future grid planning and investments.
Flexibility estimation is the first step necessary to incorporate building energy systems into demand side management programs. We extend a known method for temporal flexibility estimation from literature to a real-world residential heat pump system, solely based on historical cloud data. The method proposed relies on robust simplifications and estimates employing process knowledge, energy balances and manufacturer's information. Resulting forced and delayed temporal flexibility, covering both domestic hot water and space heating demands as constraints, allows to derive a flexibility range for the heat pump system. The resulting temporal flexibility lay within the range of 24 minutes and 6 hours for forced and delayed flexibility, respectively. This range provides new insights into the system's behaviour and is the basis for estimating power and energy flexibility - the first step necessary to incorporate building energy systems into demand side management programs.
Grid-scale electrical energy storage (EES) is a key component in cost-effective transition scenarios to renewable energy sources. The requirement of scalability favors EES approaches such as pumped-storage hydroelectricity (PSH) or compressed-air energy storage (CAES), which utilize the cheap and abundant storage materials water and air, respectively. To overcome the site restriction and low volumetric energy densities attributed to PSH and CAES, liquid-air energy storage (LAES) has been devised; however, it suffers from a rather small round-trip efficiency (RTE) and challenging storage conditions. Aiming to overcome these drawbacks, a novel system for EES is developed using solidified air (i.e., clathrate hydrate of air) as the storable phase of air. A reference plant for solidified-air energy storage (SAES) is conceptualized and modeled thermodynamically using the software CoolProp for water and air as well as empirical data and first-order approximations for the solidified air (SA). The reference plant exhibits a RTE of 52% and a volumetric storage density of 47 kWh per m3 of SA. While this energy density relates to only one half of that in LAES plants, the modeled RTE of SAES is comparable already. Since improved thermal management and the use of thermodynamic promoters can further increase the RTEs in SAES, the technical potential of SAES is in place already. Yet, for a successful implementation of the concept - in addition to economic aspects - questions regarding the stability of SA must be first clarified and challenges related to the processing of SA resolved.