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When it comes to improving the health of the general population, mHealth technologies with self-monitoring and intervention components hold a lot of promise. We argue, however, that due to various factors such as access, targeting, personal resources or incentives, self-monitoring applications run the risk of increasing health inequalities, thereby creating a problem of social justice. We review empirical evidence for “intervention-generated” inequalities, present arguments that self-monitoring applications are still morally acceptable, and develop approaches to avoid the promotion of health inequalities through self-monitoring applications.
Load shifting of resistive domestic hot water heaters has been done in Europe since the 1930s, primarily to ease the power supply during peak times. However, the pursued and already commenced energy transition in Europe changes the requirements for the underlying logic. In this more general context, demand side management is considered a viable approach to utilize the flexibility of thermal and electrochemical storage systems for buffering energy generated from renewables. In this work, an autonomous approach for demand side management of energy storage systems is developed, which is based on unidirectional communication of an incentive. This concept is then applied to the specific problem of resistive domestic hot water heaters.
The basic algorithms for an optimized operation are developed and evaluated based on simulation studies. The optimization problem considered, maps the search for the optimal heating schedule, while ensuring the temperature limits defined: Firstly, a maximum, which is defined by the hysteresis set point temperature; Secondly, during hot water draw offs, the outlet temperature should not fall below a set minimum. To establish this, the time series of hot water usage has to be predicted.
Depending on the complexity of the hot water heater model used, the formulation of the problem ranges from a linear to non-linear optimization with discontinuous constraints. The simulation studies presented, comprise a formulation as binary linear optimization problem, as well as a solution based on a heuristic direct method to solve the non-linear version. In contrast to the first linear approach, the latter takes stratification inside the tank into account. One-year simulations based on realistic hot water draw profiles are used to investigate the potentials with respect to load shift and energy efficiency improvements. Additional to assuming perfect prediction of user behavior, this work also considers the k-nearest neighbors algorithm to predict the time series. If compared to usual night-tariff switched operation, assuming perfect prediction shows 30 % savings on the electricity market when stratification is taken into account. The user prediction proposed leads to 16 % cost savings, while 6 % of the electric energy is conserved.
Based on the linear approach, a prototype is developed and used in a field test. A micro computer processes the sensor information for local data acquisition, receives electricity spot market prices up to 34 hours in advance, solves the optimization problem for this time horizon, and switches the power supply of the resistive heating element accordingly. Beside the temperature of the environment, the inlet and outlet temperatures, the temperature inside the tank is measured at five points, as well as the water volume flow rate and the electric power recorded. Two test runs of 18 days each, compare the night-tariff switched operation to the price-based optimization in a real-world environment. Results show a significant increase of 6 % in thermal efficiency during the operation based on the algorithm developed, which can be contributed to the optimization accounting for the usage expected.
To facilitate the technical and economic feasibility for retrofit-able implementations of the method proposed for autonomous demand side management, the sensors used must be kept to a minimum. A sufficiently accurate state estimation of the storage has to be achieved, to facilitate a useful model predictive control. Therefore, the last part of this work focuses on the aspect of automated system identification and state estimation of resistive domestic hot water heaters. To that end, real hot water usage profiles and schedules gathered in a field test are used in a lab setup, to collect data on the temperature distribution inside the tank during realistic operating conditions. Four different thermal models, common in literature, are considered for state estimation and system identification. Based on the data collected in the lab, they are evaluated with respect to robustness, computational costs, and estimation accuracy. Based on the observations made in the experiments, an extension of the one-node model by a single additional parameter is proposed. By this adaption, a linear temperature distribution in the lower part of the tank can be modeled during heating. The resulting model exhibits improved robustness and lower computational costs, when compared to the original model. At the same time, the average temperature in the storage tank is estimated nearly as accurate (6 % mean average percentage error) as in the case of the about 50 times more computationally expensive multi-layer model (4 % mean average percentage error).
Concept of probabilistic modeling for real-time prediction of product quality and design automation
(2018)
Product ion distributions resulting from the primary reactions of H3O+ with nine D-labeled volatile organic compounds and the subsequent sequential reactions with H2O have been determined using a Proton Transfer Reaction Time of Flight Mass Spectrometer (PTR-TOF 8000 (IONICON Analytik GmbH)) at various reduced electric field (E/N) values ranging from 80 up to 150 Td and for two different absolute humidity levels of air sample < 0.1% and 5%. The specific D-labeled compounds used in this study are acetone-d6, toluene-d8, benzene-d6, ethanol-d (C2H5OD), ethanol-d2 (CH3CD2OH), ethanol-d6, 2-propanol-d8, 2-propanol-d3 (CD3CH(OH)CH3), and isoprene-d5 (CH2CHC(CD2)CD3). With the exception of the two 2-propanol compounds, non-dissociative proton transfer is the dominant primary reaction pathway. For 2-propanol-d8 and 2-propanol-d3 the major primary reaction channel involved is dissociative proton transfer. However, unlike their undeuterated counterparts, the primary product ions undergo subsequent deuterium/hydrogen isotope exchange reactions with the ever present water in the drift tube, the extent of which of course depends on the humidity within that tube. This exchange leads to the generation of various isotopologue product ions, the product ion branching percentages of which are also
dependent on the humidity in the drift tube. This results in complex mass spectra and the distribution of product ions leads to issues of reduced sensitivity and accuracy. However, the effect of D/H exchange considerably varies between the compounds under study. In the case of acetone-d6 it is very weak (<1%), because the exchange process is not facile when the deuterium is in the methyl functional group. In comparison, the H3O+/ benzene-d6 (C6D6) reaction and sequential reactions with water result in the production of the isotopologue ions C6Dn(H7-n)+ (where n = 0–6). Changing the value of E/N and/or the humidity in the drift tube considerably affects the amount of the isotope exchange reactions and hence the resulting sequential product ion distributions. An important conclusion of the findings from this work is that care must be taken in the choice of an exogenous deuterated compound for use in breath pharmacokinetic studies using proton transfer reaction mass spectrometry; otherwise the resulting D/H exchange processes impose interpretative problems.
© 2018 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license
(http://creativecommons.org/licenses/by/4.0/).
Breath analysis offers a non-invasive and rapid diagnostic method for detecting various volatile organic compounds that could be indicators for different diseases, particularly metabolic disorders including type 2 diabetes mellitus. The development of type 2 diabetes mellitus is closely linked to metabolic dysfunction of adipose tissue and adipocytes. However, the VOC profile of human adipocytes has not yet been investigated. Gas chromatography with mass spectrometric detection and head-space needle trap extraction (two-bed Carbopack X/Carboxen 1000 needle traps) were applied to profile VOCs produced and metabolised by human Simpson Golabi Behmel Syndrome adipocytes. In total, sixteen compounds were identified to be related to the metabolism of the cells. Four sulphur compounds (carbon disulphide, dimethyl sulphide, ethyl methyl sulphide and dimethyl disulphide), three heterocyclic compounds (2-ethylfuran, 2-methyl-5-(methyl-thio)-furan, and 2-pentylfuran), two ketones (acetone and 2-pentanone), two hydrocarbons (isoprene and n-heptane) and one ester (ethyl acetate) were produced, and four aldehydes (2-methyl-propanal, butanal, pentanal and hexanal) were found to be consumed by the cells of interest. This study presents the first profile of VOCs formed by human adipocytes, which may reflect the activity of the adipose tissue enzymes and provide evidence of their active role in metabolic regulation. Our data also suggest that a previously reported increase of isoprene and sulphur compounds in diabetic patients may be explained by their production by adipocytes. Moreover, the unique features of this profile, including a high emission of dimethyl sulphide and the production of furan-containing VOCs, increase our knowledge about metabolism in adipose tissue and provide diagnostic potential for future applications.
Strain-tunable GaAs quantum dot: a nearly dephasing-free source of entangled photon pairs on demand
(2018)
Combining parallel pattern generation of electrohydrodynamic lithography with serial addressing
(2018)
Ultrafast-laser manufacture of radially emitting optical fiber diffusers for medical applications
(2018)
Black titanium dioxide in situ generated on femtosecond laser induced periodic surface structures
(2018)
Praxis und/oder Theorie
(2018)