Energietechnik und Energiewirtschaft
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A novel calorimetric technique for the analysis of gas-releasing endothermic dissociation reactions
(2020)
Graphite substrates underwent two methods of creating doped silicon carbide films via carbothermal reduction; the first method being liquid-phase processing, or dip-coating, and the second gas-phase processing, otherwise referred to as the solid-vapour reaction. The dip-coating procedure resulted in flaky coatings, while the solid-vapour reaction resulted in polycrystalline films with columnar growth that displayed promising morphological and electrical properties. The films were tested on their performance as semiconductor diodes, and proved that carbothermal reduction in the gas phase is a promising technique for creating polycrystalline silicon carbide films for the application of light-emitting diodes.
The master thesis concentrates on two different cases to generate energy from MSW. In the first case, the MSW is incinerated in an incineration plant. This approach represents the present situation in the waste treatment in large parts of the UK.
In the second case, the OFMSW is separated in a treatment facility and used in a fermentation plant. The remaining waste is again used as a feedstock in an incineration plant. The difference in the net energy yield between these two cases is investigated in this thesis.
To calculate the difference in the energy yield of case 1 and case 2, a research of the existing literature about comparisons of incineration and fermentation plants and their results are reflected and data about the MSW in the UK is collected. With the input of the literature and the researched data, a model is built which compares the two different cases of waste treatment. The results of the comparisons are then examined by varying different parameters. This step is repeated by using different input parameters. Afterwards, the results are compared and analysed.
In the next part of the thesis, an economic analysis of the incineration and fermentation combined technology plant is made. In this analysis, the investment costs, the annual profits and the annual costs of an additional fermentation plant are discussed and calculated. The result of the analysis is displayed as an amortization time calculation. The results are then analysed by varying the parameters in a sensitivity analysis.
Finally, the research question is answered and a forecast for possible plant designs with an incineration and a fermentation plant in combination are discussed.
In this thesis the effect of dc voltage bias on the equivalent series resistance (ESR) of capacitors and especially ferroelectric dielectric ceramic capacitors (FDCC) is analysed. Further the influence of the dc biased ESR on the losses of capacitors is investigated. Also piezoelectric resonances (PR) occurring in FDCCs with applied dc bias and their influence on the losses are analysed.
Therefore a measurement circuit to measure the impedance and thus the ESR of capacitors in combination with a vector network analyser (VNA) is developed. Using the developed circuit the ESR of capacitors of different technologies is measured and their behaviour with dc bias is evaluated. The losses of an FDCC are measured in a power electronic (PE) circuit with a developed calorimetric measurement system (CMS). The influence of the PR is investigated by tuning the switching frequency of the PE system and thus the frequency of the capacitor current exactly into the PR. The measured losses are then compared to a calculation based on the capacitor current harmonics and the respective ESR.
The measurements show an increase of the ESR with dc bias for all measured FDCCs. The loss measurements show a significant increase of the losses in an FDCC if the current frequency matches the PR frequency. Consequently a decrease of the PE system's efficiency is measured. The loss calculations do not exactly match the measurements but there is a systematic deviation of the same order for all measurements.
In times of global climate change, it is increasingly important to investigate emissions and resource consumption of all machines and, if possible, to improve them. This includes within the transport sector car ferries.
In order to reduce the environmental impacts of car ferries, the electrification has penetrated into this sector, which has led to the world's first fully electric car ferry. One of the most important components to operate this ferry is the energy storage. Not only the battery storage of the ferry itself is needed, but also an onshore battery storage system is needed to support the electrical grid.
The present study examines how storage technologies and concepts can impact the environment considering the world's first all-electric car ferry, MF Ampere, which operates in Norway.
To examine this, the current onshore battery storage system is compared to a concrete sphere storage system. For this purpose, data from the first test run of this new storage technology, which was successfully carried out by the Fraunhofer Institute in 2016, is considered. Subsequently, a life cycle assessment of the two storage systems is carried out to compare the environmental impacts.
The concrete sphere storage system performs better for 15 of 17 impact categories compared to the existing onshore battery storage system. Depending on the impact category the impact reduction is about 2% to 8%.
Nevertheless, it is difficult to estimate how long the useful life and how good the efficiency of the concrete ball storage will be, since no system of this size has been tested yet. Also, the costs of the concrete sphere storage system have not been considered.
The humidification dehumidification (HDH) cycle is a process for thermal water treatment. Many studies were carried out investigating operation of an HDH cycle with water and seawater as working liquid. Currently research into other areas of application is limited. Exchanging the working liquid in the humidifier from seawater to a water oil emulsion and investigating its behavioural changes is the basis for the expansion into applications such as bilge water treatment. This master’s thesis covers analysis of the behaviour of an HDH cycle operated with a water oil emulsion. The main elements are (1) proof of concept for operation of the HDH cycle with a water oil emulsion, (2) comparison of measurements and thermodynamic calculations, (3) investigation of the impact of operating parameters and (4) optical analysis of the bubbly flow in water and oil.
Operation of the HDH cycle using water oil emulsion was shown to be feasible with a small change to the setup previously used for investigations with seawater as working liquid. To keep the emulsion from separating into its individual parts, constant movement of the working liquid needs to be ensured. For this a magnetic stirrer was introduced into the bubble column humidifier (BCH) used. In a batch process an oil concentration of >97 % was reached without visible traces of oil in the produced condensate.
Comparison of the measured and thermodynamically evaluated productivity shows that measured productivity is higher. The proposed explanation for this is supersaturation of air at the BCH exit. Further investigation into this phenomenon is needed to confirm this hypothesis.
Influential parameters investigated are (1) liquid temperature, (2) superficial air velocity and (3) sieve plate orifice diameter. Increase of liquid temperature results in an exponential increase in productivity. At superficial air velocities up to 3 cm/s productivity increases with superficial air velocity. For superficial air velocities higher than 3 cm/s productivity plateaus. At low superficial air velocity, an increase of sieve plate orifice diameter results in increasing productivity. Further increase of the sieve plate orifice diameter inverses this phenomenon.
Bubbly flow in water and oil is influenced by the different viscosities of the liquids. Water creates small bubbles of similar size at low superficial air velocities. At superficial air velocities >2 cm/s turbulences start to increase and finely dispersed bubbles are present in the water. Bubbly flow in oil creates larger bubbles at all superficial air velocities. The airflow transitions to plug flow at velocities of 3 cm/s and above.
Result from this master’s thesis can be used for as a basis to broaden the understanding of the HDH cycle and find new areas of applications.
In the residential construction industry, the focus on energy efficiency and cost effectiveness has been gaining importance. In order to achieve these contradicting objectives, a shift towards a reduced complexity in building practices can be observed.
Within the HVAC sector, the Tempering method for space heating has received particular attention as an alternative way to heat museums and buildings worthy of preservation.
In spite of the simplified design, this space heating system is claimed to offer significant advantages in its present field of application.
This study evaluates the implementation of Tempering in the residential context. So far, there is no scientific research on the implementation of Tempering in energy efficient-dwellings.
This master thesis provides initial results on achievable heat flux values, the impact on heat generation efficiency, the inherent installation costs as well as the particular
consequences in terms of end energy consumption of the building as a whole. The findings are compared to the individual performances of well-established heat emission approaches.
By means of a numerical analysis and a case study on a real-case single-family home, it is found that the heat flux values of Tempering systems suffice for the implementation within buildings, which comply with the low-energy building standard. Comparing radiant walls, radiant floors and radiators, the inherent installation costs are lowest for Tempering and radiant floors. The impact on the end energy consumption depends largely on the utilised heat generation system. With a gas-condensing boiler, Tempering performs equal to the radiant systems. When a ground source heat pump system is installed, however, Tempering performs poorly and accounts for a significantly increased energy consumption. Radiator systems are found to be the most energy-efficient method for space heating in both cases.
In recent years, numerous studies around the world have examined the environmental potential of biochar to determine whether it can help address climate challenges. Several of these studies have used the Life Cycle Assessment (LCA) method to evaluate the environmental impacts of biochar systems. However, studies focus mainly on biochar obtained from pyrolysis, while the number of studies on biochar from gasification is small.
To contribute to the current state of LCA research on biochar from gasification, LCA was performed for biochar, electricity, and heat from a wood gasification plant in Vorarlberg, Austria. Woodchips from local woods are used as biomass feedstock to produce energy, i.e., electricity and heat. Thereby, biochar is obtained as a side product from gasification. The production of syngas and biochar takes place in a floating fixed-bed gasifier. Eventually, the syngas is converted to electricity in a gas engine and fed to the power grid. Throughout different stages within the gasification process, heat is obtained and fed into local heat grid to be delivered to customers. The biochar produced complies with the European Biochar Industry (EBI) guidelines and is used on a nearby farm for manure treatment and eventually for soil application. Thereby, the effect of biochar used for manure treatment is considered to reduce emissions occurring from manure, i.e., nitrogen monoxide (N2O). Further, the CO2 sequestration potential of biochar, i.e., removal of CO2 from the atmosphere and long-term storage, is considered. Several constructions, such as the construction of the gasification system and the heating grid, are included in the evaluation.
As input related reference flow, 1 kg of woodchips with water content of 40 % is used. Three functionals units are eventually obtained, i.e., 0.17 kg of biochar applied to soil, 4.47 MJ of heat and 2.82 MJ of electricity, each per reference flow. The results for Global Warming Potential (GWP) for biochar is – 274.7*10 - 3 kg CO2eq per functional unit, which corresponds to – 1.6 kg CO2eq per 1 kg biochar applied to soil. The GWP for heat results in 17.1*10 - 3 CO2eq per functional unit, which corresponds to 3.6*10 - 3 kg CO2eq per 1 MJ. For electricity, a GWP of 38.1*10 - 3 kg CO2eq per functional unit is obtained, which is equivalent to 13.5*10 - 3 kg CO2eq per 1 MJ.
The calculation was performed using SimaPro Version 9.1 and the ReCiPe method with hierarchist perspective.
This study deals with the energy situation in Ny-Ålesund, an Arctic research station on the archipelago Svalbard, and aims at analysing the technical feasability of a transition to renewable energies by taking into consideration both the environmental and climatic impediments.
The analysis is based on a 27 year long collection of authentic meteorological data with all its strong fluctuations, seasonal as well as yearly. Great emphasis was put on the discussion of tried-and-tested renewable technologies that were compared to a new wind-based energy device that has yet to be tested for its reliability in the harsh environment of notably the Arctic winter. Meticulous calculations lead to the result that bifacial solar modules are an efficient means even in months when the sun stands low and their combination with wind-based devices prove to generate a maximum output. Geothermal energy seems to be promising in the region, but could not be evaluated due to a crucial lack of relevant data.
The study comes to the conclusion that the research station of Ny-Ålesund could well rely on a combination of renewable energy devices to cover its energy load, but needs to keep a back-up system of diesel run generators to bridge short periods of possible dysfunctions or standstills due to meteorological circumstances. Battery storage could only contribute to solve the problem of an unfortunate interruption of the energy supply, but it cannot serve as the entire back-up system since, at present, the need would go beyond all possible dimensions.