Forschungszentrum Energie
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Greater specific energy densities in lithium-ion batteries can be achieved by using three-dimensional (3D) porous current collectors, which allow for greater areal mass loadings of the electroactive material. In this paper, we present the use of embroidered current collectors for the preparation of thick, pouch-type Li-ion batteries. Experiments were performed on LiFePO 4 (LFP) water-based slurries using styrene-butadiene rubber (SBR) as binder and sodium carboxymethyl cellulose (CMC) as thickener, and formulations of different rheological characteristics were investigated. The electrochemical performance (cyclic voltammetry, rate capability) and morphological characteristics of the LFP half-pouch cells (X-ray micro computed tomography and scanning electron microscopy) were compared between the formulations. An optimum electrode formulation was identified, and a mechanism is proposed to explain differences between the formulations. With the optimum electrode formulation, 350 µm casted electrodes with high mechanical stability were achieved. Electrodes exhibited 4–6 times greater areal mass loadings (4–6 mAh cm −2 ) and 50% greater electroactive material weight than with foils. In tests of half- and full-pouch embroidered cells, a 50% capacity utilization at 1C-rate and 11% at 2C-rate were observed, with a full recovery at C/5-rate. The cycling stability was also maintained over 55 cycles.
If left uncontrolled, electric vehicle charging poses severe challenges to distribution grid operation. Resulting issues are expected to be mitigated by charging control. In particular, voltage-based charging control, by relying only on the local measurements of voltage at the point of connection, provides an autonomous communication-free solution. The controller, attached to the charging equipment, compares the measured voltage to a reference voltage and adapts the charging power using a droop control characteristic. We present a systematic study of the voltage-based droop control method for electric vehicles to establish the usability of the method for all the currently available residential electric vehicle charging possibilities considering a wide range of electric vehicle penetrations. Voltage limits are evaluated according to the international standard EN50160, using long-term load flow simulations based on a real distribution grid topology and real load profiles. The results achieved show that the voltage-based droop controller is able to mitigate the under voltage problems completely in distribution grids in cases either deploying low charging power levels or exhibiting low penetration rates. For high charging rates and high penetrations, the control mechanism improves the overall voltage profile, but it does not remedy the under voltage problems completely. The evaluation also shows the controller’s ability to reduce the peak power at the transformer and indicates the impact it has on users due to the reduction in the average charging rates. The outcomes of the paper provide the distribution grid operators an insight on the voltage-based droop control mechanism for the future grid planning and investments.
Violation-mitigation-based method for PV hosting capacity quantification in low voltage grids
(2022)
Hosting capacity knowledge is of great importance for distribution utilities to assess the amount of PV capacity possible to accommodate without troubling the operation of the grid. In this paper, a novel method to quantify the hosting capacity of low voltage grids is presented. The method starts considering a state of fully exploited building rooftop solar potential. A downward process is proposed - from the starting state with expected violations on the grid operation to a state with no violations. In this process, the installed PV capacity is progressively reduced. The reductions are made sequentially and selectively aiming to mitigate specific violations: nodes overvoltage, lines overcurrent and transformer overloading. Evaluated on real data of fourteen low voltage grids from Austria, the method proposed exhibits benefits in terms of higher hosting capacities and lower computational costs compared to stochastic methods. Furthermore, it also quantifies hosting capacity expansions achievable by overcoming the effect of the violations. The usage of a potential different from solar rooftops is also presented, demonstrating that a user-defined potential allows to quantify the hosting capacity in a more general setting with the method proposed.
Grey Box models provide an important approach for control analysis in the Heating, Ventilation and Air Conditioning (HVAC) sector. Grey Box models consist of physical models where parameters are estimated from data. Due to the vast amount of component models that can be found in literature, the question arises, which component models perform best on a given system or dataset? This question is investigated systematically using a test case system with real operational data. The test case system consists of a HVAC system containing an energy recovery unit (ER), a heating coil (HC) and a cooling coil (CC). For each component, several suitable model variants from the literature are adapted appropriately and implemented. Four model variants are implemented for the ER and five model variants each for the HC and CC. Further, three global optimization algorithms and four local optimization algorithms to solve the nonlinear least squares system identification are implemented, leading to a total of 700 combinations. The comparison of all variants shows that the global optimization algorithms do not provide significantly better solutions. Their runtimes are significantly higher. Analysis of the models shows a dependency of the model accuracy on the number of total parameters.
Grid-scale electrical energy storage (EES) is a key component in cost-effective transition scenarios to renewable energy sources. The requirement of scalability favors EES approaches such as pumped-storage hydroelectricity (PSH) or compressed-air energy storage (CAES), which utilize the cheap and abundant storage materials water and air, respectively. To overcome the site restriction and low volumetric energy densities attributed to PSH and CAES, liquid-air energy storage (LAES) has been devised; however, it suffers from a rather small round-trip efficiency (RTE) and challenging storage conditions. Aiming to overcome these drawbacks, a novel system for EES is developed using solidified air (i.e., clathrate hydrate of air) as the storable phase of air. A reference plant for solidified-air energy storage (SAES) is conceptualized and modeled thermodynamically using the software CoolProp for water and air as well as empirical data and first-order approximations for the solidified air (SA). The reference plant exhibits a RTE of 52% and a volumetric storage density of 47 kWh per m3 of SA. While this energy density relates to only one half of that in LAES plants, the modeled RTE of SAES is comparable already. Since improved thermal management and the use of thermodynamic promoters can further increase the RTEs in SAES, the technical potential of SAES is in place already. Yet, for a successful implementation of the concept - in addition to economic aspects - questions regarding the stability of SA must be first clarified and challenges related to the processing of SA resolved.
Increasing electric vehicle penetration leads to undesirable peaks in power if no proper coordination in charging is implemented. We tested the feasibility of electric vehicles acting as flexible demands responding to power signals to minimize the system peaks. The proposed hierarchical autonomous demand side management algorithm is formulated as an optimal power tracking problem. The distribution grid operator determines a power signal for filling the valleys in the non-electric vehicle load profile using the electric vehicle demand flexibility and sends it to all electric vehicle controllers. After receiving the control signal, each electric vehicle controller re-scales it to the expected individual electric vehicle energy demand and determines the optimal charging schedule to track the re-scaled signal. No information concerning the electric vehicles are reported back to the utility, hence the approach can be implemented using unidirectional communication with reduced infrastructural requirements. The achieved results show that the optimal power tracking approach has the potential to eliminate additional peak demands induced by electric vehicle charging and performs comparably to its central implementation. The reduced complexity and computational overhead permits also convenient deployment in practice.
Industrial demand side management has shown significant potential to increase the efficiency of industrial energy systems via flexibility management by model-driven optimization methods. We propose a grey-box model of an industrial food processing plant. The model relies on physical and process knowledge and mass and energy balances. The model parameters are estimated using a predictive error method. Optimization methods are applied to separately reduce the total energy consumption, total energy costs and the peak electricity demand of the plant. A viable potential for demand side management in the plant is identified by increasing the energy efficiency, shifting cooling power to low price periods or by peak load reduction.
Clathrate hydrates, or hydrates for short, are inclusion compounds in which water molecules form a hydrogen-bonded host lattice that accommodates the guest molecules. While vast amounts of hydrates are known to exist in seafloor sediments and in the permafrost on Earth, these occurrences might be dwarfed by the amounts of hydrates occurring in space and on celestial bodies. Since methane is the primary guest molecule in most of the natural occurrences on Earth, hydrates are considered a promising source of energy. Moreover, the ability of one volume of hydrate to store about 170 volumes of gas, make hydrates a promising functional material for various industrial applications. While the static properties of hydrates are reasonably well known, the dynamics of hydrate formation and decomposition are insufficiently understood. For instance, the stochastic period of hydrate nucleation, the memory effect, and the self-preservation phenomenon complicate the development of predictive models of hydrate dynamics. Additionally, the influence of meso- and macroscopic defects as well as the roles of mass and heat transport on different length scales remain to be clarified.
Due to its non-invasive and non-destructive nature and the high spatial resolution of approx. 1µm or even less, micro-computed X-ray attenuation tomography ( µCT ) seems to be the perfect method for the study of the evolving structures of forming or decomposing hydrates on the meso- and macroscopic length scale. However, for the naturally occurring hydrates of low atomic number guests the contrast between hydrate, ice, and liquid water is typically very weak because of similar X-ray attenuation coefficients. So far, good contrast was only restricted to synchrotron beamline experiments which utilize the phase information of monochromatic X-rays.
In this thesis it is shown that with the help of a newly developed sample cell, a contrast between the hydrate and the ice phase sufficiently good for the reliable segmentation of the materials can also be achieved in conventional tube-based µCT. An accurate pressure and temperature management, i.e., the added functionality of the cell, further allows for cross-correlation of structural and thermodynamic data. The capability of this µCT setup is demonstrated in a series of studies on the formation and decomposition of hydrates which yield new insights for the development of a novel route to hydrate synthesis. At last, this thesis points towards possibilities how better models of hydrate formation and decomposition can be developed with the aid of µCT and computer simulations.
Der Befeuchtungs-Entfeuchtungs-Prozess (HDH) wird zur Meerwasserentsalzung eingesetzt und bietet Vorteile wie die Nutzung von Wärme auf einem geringen Temperaturniveau sowie die Realisierbarkeit dezentraler Anlagen. Bei diesem Prozess wird Luft im Kontakt mit warmem Salzwasser im Optimalfall bis zur Sättigung befeuchtet. Die feuchte Luft wird anschließend abgekühlt, um das in ihr befindliche Wasser wieder zu kondensieren. Obwohl der HDH-Prozess bereits mehrfach Gegenstand der Forschung war, besitzt die Effizienz des Prozesses nach wie vor ein hohes Steigerungspotential. Das Ziel dieser Masterarbeit besteht in der Konzeption und der Realisierung eines Versuchsaufbaus zur Analyse der Befeuchtung von Luft in Wasser. Dabei soll der Untersuchungsgegenstand zukünftiger Versuche die Befeuchtereinheit sein, die ein hohes Potential hinsichtlich der Effizienzsteigerung von HDH-Systemen bietet. In neueren Publikationen wurden zum Einsatz in HDH-Systemen Blasensäulenbefeuchter als eine bessere Alternative zu Festbettbefeuchtern oder Sprühtürmen vorgeschlagen, weswegen die Befeuchtung in solchen Aggregaten näher untersucht werden muss. Das Hauptziel dieser Masterarbeit ist ein Versuchsaufbau, der die Möglichkeit bietet, die Parameter, die die Befeuchtung von Luft in einer Blasensäule maßgeblich beeinflussen, mit einer ausreichenden Genauigkeit zu messen, um aus diesen Messungen semiempirische Korrelationen ableiten zu können. Die die Befeuchtung von Luft maßgeblich beeinflussenden Parameter sind die Wassertemperatur, der Füllstand im Befeuchter, die Luftgeschwindigkeit sowie die Blasengröße.
Zum aktuellen Stand ist ein HDH-System, bestehend aus einem Blasensäulenbefeuchter, einem Querstromwärmetauscher sowie einer Dosierpumpe errichtet. Mit diesem System können wissenschaftlich notwendige empirische Zusammenhänge zwischen den die Befeuchtung beeinflussenden Parametern und der Befeuchtung von Luft aus Versuchen abgeleitet werden. Die im Versuchsaufbau verbaute Messtechnik wurde derart ausgewählt, dass deren Einfluss auf das System so gering wie möglich gehalten werden kann.
Mit dem Versuchsaufbau ist es darüber hinaus möglich, invasive Messmethoden mit nicht invasiven Messmethoden direkt zu vergleichen. Um eine für die Messungen optimale Befeuchtergeometrie zu finden, sind zwei Blasensäulenbefeuchtereinheiten aufgebaut, davon eine mit planarem und eine mit zylindrischem Querschnitt. So ist es möglich, im Direktvergleich die Vor- und Nachteile der Querschnittsanordnungen nachzuweisen. Die Komponenten der beiden HDH-Systeme wurden anhand von wissenschaftlich akzeptierten Modellen bezüglich der dazugehörigen Wärmeübertragungsraten, der Wärmeverluste und der Druckverluste ausgelegt.
Eine Modellierung des Stoffübergangs in der Blasensäule ist durchgeführt. Anhand dieser Modellierung konnte der Stoffübergangskoeffizient in der Grenzschicht zwischen Luftblase und Flüssigkeitssäule ermittelt werden. Anhand einer Massenbilanz konnte über den Stoffübergangskoeffizienten die Austrittswasserbeladung der feuchten Luft modelliert werden.
Die Funktionalität des Versuchsaufbaus ist gegeben. Messungen des Gasgehalts zeigen eine sehr gute Übereinstimmung mit wissenschaftlich anerkannten Korrelationen zum Gasgehalt. Die optische Zugänglichkeit des Versuchsaufbaus ist evaluiert und lässt die Tendenz ableiten, dass sich ein planarer Befeuchterquerschnitt in Verbindung mit Fotoaufnahmen von den durchgeführten Varianten am besten zur digitalen Bildanalyse eignet.
Aus den Experimenten, die am realisierten Versuchsaufbau durchgeführt werden, kann sich eine allgemeingültige Auslegungsgrundlage für Versuchsaufbauten ergeben, mit denen Messungen der Befeuchtung von Luft in Blasensäulenbefeuchtern durchgeführt werden sollen.
The impact of global warming and climate change has forced countries to introduce strict policies and decarbonization goals toward sustainable development. To achieve the decarbonization of the economy, a substantial increase of renewable energy sources is required to meed energy demand and to transition away from fossil fuels. However, renewables are sensitive to environmental conditions, which may lead to imbalances between energy supply and demand. Battery energy storage systems are gaining more attention for balancing energy systems in existing grid networks at various levels such as bulk power management, transmission and distribution, and for end-users. Integrating battery energy storage systems with renewables can also solve reliability issues related to transient energy production and be used as a buffer source for electrical vehicle fast charging. Despite these advantages, batteries are still expensive and typically built for a single application – either for an energy- or power-dense application – which limits economic feasibility and flexibility. This paper presents a theoretical approach of a hybrid energy storage system that utilizes both energy- and power-dense batteries serving multiple grid applications. The proposed system will employ second use electrical vehicle batteries in order to maximise the potential of battery waste. The approach is based on a survey of battery modelling techniques and control methods. It was found that equivalent circuit models as well as unified control methods are best suited for modelling hybrid energy storages for grid applications. This approach for hybrid modelling is intended to help accelerate the renewable energy transition by providing reliable energy storage.