624 Ingenieurbau und Umwelttechnik
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Vast amounts of oily wastewater are byproducts of the petrochemical and the shipping industry and to this day frequently discharged into water bodies either without or after insufficient treatment. To alleviate the resulting pollution, water treatment processes are in great demand. Bubble column humidifiers (BCHs) as part of humidification–dehumidification systems are predestined for such a task, since they are insensitive to different feed liquids, simple in design and have low maintenance requirements. While humidification in a bubble column has been investigated plentiful for desalination, a systematic investigation of oily wastewater treatment is missing in literature. We filled this gap by analyzing the treatment of an oil–water emulsion experimentally to derive recommendations for future design and operation of BCHs. Our humidity measurements indicate that the air stream is always saturated after humidification for a liquid height of only 10 cm. A residual water mass fraction of 3.5 wt% is measured after a batch run of six hours. Furthermore, continuous measurements show that an increase in oil mass fraction leads to a decrease in system productivity especially for high oil mass fractions. This decrease is caused by the heterogeneity of the liquid temperature profile. A lower liquid height mitigates this heterogeneity, therefore decreasing the heat demand and improving the overall efficiency. The oil content of the produced condensate is below 15 ppm, allowing discharge into various water bodies. The results of our systematic investigation prove suitability and indicate a strong future potential for the use of BCHs in oily wastewater treatment.
Bubble columns are recently used for the humidification of air in water treatment systems and fuel cells. They are well applicable due to their excellent heat and mass transfer and their low technical complexity. To design and operate such devices with high efficiency, the humidification process and the impact of the operating parameters need to be understood to a sufficient degree. To extend this knowledge, we use a refined and novel method to determine the volumetric air–liquid heat and mass transfer coefficients and the humidifier efficiency for various parametric settings. The volumetric transfer coefficients increase with both of the superficial air velocity and the liquid temperature. It is further shown that the decrease of vapor pressure with an increase of the salinity results in a corresponding decrease in the outlet humidity ratio. In contrast to previous studies, liquid heights smaller than 0.1 m are investigated and significant changes in the humidifier efficiency are seen in this range. We present the expected humidifier efficiency with respect to the superficial air velocity and the liquid height in an efficiency chart, such that optimal operating conditions can be determined. Based on this efficiency chart, recommendations for industrial applications as well as future scientific challenges are drawn.
Bubble column humidifiers (BCHs) are frequently used for the humidification of air in various water treatment applications. A potential but not yet profoundly investigated application of such devices is the treatment of oily wastewater. To evaluate this application, the accumulation of an oil-water emulsion using a BCH is experimentally analyzed. The amount of evaporating water vapor can be evaluated by measuring the humidity ratio of the outlet air. However, humidity measurements are difficult in close to saturated conditions, as the formation of liquid droplets on the sensor impacts the measurement accuracy. We use a heating section after the humidifier, such that no liquid droplets are formed on the sensor. This enables us a more accurate humidity measurement. Two batch measurement runs are conducted with (1) tap water and (2) an oil-water emulsion as the respective liquid phase. The humidity measurement in high humidity conditions is highly accurate with an error margin of below 3 % and can be used to predict the oil concentration of the remaining liquid during operation. The measured humidity ratio corresponds with the removed amount of water vapor for both tap water and the accumulation of an oil-water emulsion. Our measurements show that the residual water content
in the oil-water emulsion is below 4 %.
Wärmepumpen werden als vielversprechende Lösung zur Dekarbonisierung des Gebäudesektors angesehen. Konventionelle Kältemittel, die als direkte Emissionen aus Wärmepumpensystemen austreten, stellen insbesondere vor dem Hintergrund steigender Installationszahlen ein relevantes Treibhauspotenzial dar. Natürliche Kältemittel verfügen über ein geringes Treibhauspotenzial und können daher zur Substitution konventioneller Kältemittel verwendet werden. Dennoch werden sie bislang nicht im großen Maßstab eingesetzt. Es bedarf weiterer Studien und Anreize, um den Einsatz natürlicher Kältemittel voranzubringen. In dieser Fallstudie erfolgt anhand eines Referenzprojektes ein simulativer Vergleich zweier reversibler Luft-Wasser-Wärmepumpen. Im Referenzfall wird das konventionelle Kältemittel R32 verwendet, als Alternative dient das natürliche Kältemittel R290. Die beiden Systeme werden hinsichtlich ihrer Effizienz, Klimawirksamkeit und Wirtschaftlichkeit verglichen. Die notwendigen Berechnungen basieren auf einem kalibrierten Simulationsmodell des Gebäudes und der Anlage. Die Ergebnisse zeigen einen energetischen und ökologischen Vorteil für R290. Im Heizbetrieb, der den Hauptteil des thermischen Energiebedarfs im Referenzprojekt ausmacht, erreicht die Wärmepumpe mit R290 eine um 9% höhere Jahresarbeitszahl. Im Gegensatz dazu erzielt die R32-Wärmepumpe eine um 12% höhere Jahresarbeitszahl im Kühlbetrieb. Durch die höhere Effizienz im Heizbetrieb und das niedrigere Treibhauspotenzial des Kältemittels liegen die Emissionen durch den Betrieb der R290-Wärmepumpe um 17% unter denen der R32-Wärmepumpe. Der wirtschaftliche Vergleich der beiden Systeme fällt aufgrund höherer Investitionskosten zum Nachteil der R290-Wärmepumpe aus.
The humidification-dehumidification process (HDH) for desalination is a promising technology to address water scarcity issues in rural regions. However, a low humidifier efficiency is a weakness of the process. Bubble column humidifiers (BCH) are promising for HDH, as they provide enhanced heat and mass transfer and have low maintenance requirements. Previous studies of HDH-systems with BCHs draw different conclusions regarding the impact of superficial air velocity and liquid height on the humidification. Furthermore, the impact of flow characteristics has never been investigated systematically at all. In this study, an optimized BCH test setup that allows for optical analysis of the humidifier is used and evaluated. Our test setup is validated, since the influence of water temperature on the humidification, which is exponential, is reproduced. Measurements with seawater show that the normalised system productivity is increased by about 56 % with an increase in superficial air velocity from 0.5 to 5 cm/s. Furthermore, the system productivity is increased by around 29 % with an increase in liquid height from 60 to 378 mm. While the impact of superficial air velocity can be traced back to temperature changes at the humidifier and dehumidifier outlets, the impact of liquid height is shown to be caused by a smaller heat loss surface in the humidifier with an increase in liquid height. For the impact of sieve plate orifice diameter, a clear influence on the humidification is not apparent, this parameter needs to be investigated further. Finally, our new test setup allows for analysing the humidification of air (1) in a systematic way, (2) in relevant measurement ranges and (3) in comparison with optical analyses of the flow characteristics.
The humidification dehumidification (HDH) cycle is a process for thermal water treatment. Many studies were carried out investigating operation of an HDH cycle with water and seawater as working liquid. Currently research into other areas of application is limited. Exchanging the working liquid in the humidifier from seawater to a water oil emulsion and investigating its behavioural changes is the basis for the expansion into applications such as bilge water treatment. This master’s thesis covers analysis of the behaviour of an HDH cycle operated with a water oil emulsion. The main elements are (1) proof of concept for operation of the HDH cycle with a water oil emulsion, (2) comparison of measurements and thermodynamic calculations, (3) investigation of the impact of operating parameters and (4) optical analysis of the bubbly flow in water and oil.
Operation of the HDH cycle using water oil emulsion was shown to be feasible with a small change to the setup previously used for investigations with seawater as working liquid. To keep the emulsion from separating into its individual parts, constant movement of the working liquid needs to be ensured. For this a magnetic stirrer was introduced into the bubble column humidifier (BCH) used. In a batch process an oil concentration of >97 % was reached without visible traces of oil in the produced condensate.
Comparison of the measured and thermodynamically evaluated productivity shows that measured productivity is higher. The proposed explanation for this is supersaturation of air at the BCH exit. Further investigation into this phenomenon is needed to confirm this hypothesis.
Influential parameters investigated are (1) liquid temperature, (2) superficial air velocity and (3) sieve plate orifice diameter. Increase of liquid temperature results in an exponential increase in productivity. At superficial air velocities up to 3 cm/s productivity increases with superficial air velocity. For superficial air velocities higher than 3 cm/s productivity plateaus. At low superficial air velocity, an increase of sieve plate orifice diameter results in increasing productivity. Further increase of the sieve plate orifice diameter inverses this phenomenon.
Bubbly flow in water and oil is influenced by the different viscosities of the liquids. Water creates small bubbles of similar size at low superficial air velocities. At superficial air velocities >2 cm/s turbulences start to increase and finely dispersed bubbles are present in the water. Bubbly flow in oil creates larger bubbles at all superficial air velocities. The airflow transitions to plug flow at velocities of 3 cm/s and above.
Result from this master’s thesis can be used for as a basis to broaden the understanding of the HDH cycle and find new areas of applications.
