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We have demonstrated micromachining of bulk 3C silicon carbide (3C- SiC) wafers by employing 1028nm wavelength femtosecond laser pulses of energy less than 10 nJ directly from a femtosecond laser oscillator, thus eliminating the need for an amplified system and increasing the micromachining speed by more than four orders of magnitude.
We have investigated the ablation behaviour of single crystal SrTiO3 <100> with focus on the influence of the pulse duration at a wavelength of 248 nm. The experiments were performed with KrF-excimer lasers with pulse durations of 34 ns and 500 fs, respectively. Femtosecond-ablation turns out to be more efficient by one order of magnitude and to eliminate the known problem of cracking of SrTiO3 during laser machining with longer pulses. In addition, the cavities ablated with femtosecond pulses display a smoother surface with no indication of melting and well-defined, sharp edges. These effects can be explained by the reduced thermal shock effect on the material by using ultrashort pulses.
Modern portable electronic devices have seen component heat load increasing, while the space available for heat dissipation has decreased. This requires the thermal management system to be optimized to attain the high performance heat sink. Heat sinks plays a major role for dissipating heat in electronic devices. Phase change material (PCM) is used to enhance the heat dissipation in heat sink. This paper reports the results of an experimental investigation of the performance of Pin fin heat sinks filled with phase change materials for thermal management of electronic devices. The experimental set ups are prepared with the graphical programming language with Lab VIEW (Laboratory Virtual Instruments for Engineering Workbench. Three different types of Pin fin Heat sink with and without PCM are investigated based on different operational timings and the temperature is acquired with the help of Data Acquisition Card (DAQ). The results indicated that the inclusion of the PCM could stabilize the temperature for a longer period and reduce the heating rates and peak temperatures of heat sink with increasing the number of fins can enhance the thermal performance of electronic devices.
This paper presents a project developed at the K.S.Rangasamy College of Technology (Tamilnadu,India) aimed at designing, implementing, and testing an autonomous multipurpose vehicle with safe, efficient, and economic operation. This autonomous vehicle moves through the crop lines of a Agricultural land and performs tasks that are tedious and/or hazardous to the farmers. First, it has been equipped for spraying, but other configurations have also been designed, such as: a seeding ,plug platform to reach the top part of the plants to perform different tasks (pruning, harvesting, etc.), and a trailer to transport the fruits, plants, and crop waste.
The goal of this paper is to design a low-loss 1 x 32 Y-branch optical splitter for optical transmission systems, using two different design tools employing Beam Propagation Method. As a first step, a conventional 1 x 32 Y-branch splitter was designed and simulated in two-dimensional environment of OptiBPM photonic tool. The simulated optical properties feature high loss, high asymmetric splitting ratio and a large size of the designed structure, too. In the second step of this work we propose an optimization of the conventional splitter design leading to suppression of the asymmetric splitting ratio to one-third of its initial value and to the improvement of the losses by nearly 2 dB. In addition, 50% size reduction of the designed structure was also achieved. This length-optimized low-loss splitter was then modelled in a three-dimensional environment of RSoft photonic tool and the simulated results confirm the strong improvement of the optical properties.
The master thesis concentrates on two different cases to generate energy from MSW. In the first case, the MSW is incinerated in an incineration plant. This approach represents the present situation in the waste treatment in large parts of the UK.
In the second case, the OFMSW is separated in a treatment facility and used in a fermentation plant. The remaining waste is again used as a feedstock in an incineration plant. The difference in the net energy yield between these two cases is investigated in this thesis.
To calculate the difference in the energy yield of case 1 and case 2, a research of the existing literature about comparisons of incineration and fermentation plants and their results are reflected and data about the MSW in the UK is collected. With the input of the literature and the researched data, a model is built which compares the two different cases of waste treatment. The results of the comparisons are then examined by varying different parameters. This step is repeated by using different input parameters. Afterwards, the results are compared and analysed.
In the next part of the thesis, an economic analysis of the incineration and fermentation combined technology plant is made. In this analysis, the investment costs, the annual profits and the annual costs of an additional fermentation plant are discussed and calculated. The result of the analysis is displayed as an amortization time calculation. The results are then analysed by varying the parameters in a sensitivity analysis.
Finally, the research question is answered and a forecast for possible plant designs with an incineration and a fermentation plant in combination are discussed.
In the residential construction industry, the focus on energy efficiency and cost effectiveness has been gaining importance. In order to achieve these contradicting objectives, a shift towards a reduced complexity in building practices can be observed.
Within the HVAC sector, the Tempering method for space heating has received particular attention as an alternative way to heat museums and buildings worthy of preservation.
In spite of the simplified design, this space heating system is claimed to offer significant advantages in its present field of application.
This study evaluates the implementation of Tempering in the residential context. So far, there is no scientific research on the implementation of Tempering in energy efficient-dwellings.
This master thesis provides initial results on achievable heat flux values, the impact on heat generation efficiency, the inherent installation costs as well as the particular
consequences in terms of end energy consumption of the building as a whole. The findings are compared to the individual performances of well-established heat emission approaches.
By means of a numerical analysis and a case study on a real-case single-family home, it is found that the heat flux values of Tempering systems suffice for the implementation within buildings, which comply with the low-energy building standard. Comparing radiant walls, radiant floors and radiators, the inherent installation costs are lowest for Tempering and radiant floors. The impact on the end energy consumption depends largely on the utilised heat generation system. With a gas-condensing boiler, Tempering performs equal to the radiant systems. When a ground source heat pump system is installed, however, Tempering performs poorly and accounts for a significantly increased energy consumption. Radiator systems are found to be the most energy-efficient method for space heating in both cases.
In times of global climate change, it is increasingly important to investigate emissions and resource consumption of all machines and, if possible, to improve them. This includes within the transport sector car ferries.
In order to reduce the environmental impacts of car ferries, the electrification has penetrated into this sector, which has led to the world's first fully electric car ferry. One of the most important components to operate this ferry is the energy storage. Not only the battery storage of the ferry itself is needed, but also an onshore battery storage system is needed to support the electrical grid.
The present study examines how storage technologies and concepts can impact the environment considering the world's first all-electric car ferry, MF Ampere, which operates in Norway.
To examine this, the current onshore battery storage system is compared to a concrete sphere storage system. For this purpose, data from the first test run of this new storage technology, which was successfully carried out by the Fraunhofer Institute in 2016, is considered. Subsequently, a life cycle assessment of the two storage systems is carried out to compare the environmental impacts.
The concrete sphere storage system performs better for 15 of 17 impact categories compared to the existing onshore battery storage system. Depending on the impact category the impact reduction is about 2% to 8%.
Nevertheless, it is difficult to estimate how long the useful life and how good the efficiency of the concrete ball storage will be, since no system of this size has been tested yet. Also, the costs of the concrete sphere storage system have not been considered.
Breath analysis offers a non-invasive and rapid diagnostic method for detecting various volatile organic compounds that could be indicators for different diseases, particularly metabolic disorders including type 2 diabetes mellitus. The development of type 2 diabetes mellitus is closely linked to metabolic dysfunction of adipose tissue and adipocytes. However, the VOC profile of human adipocytes has not yet been investigated. Gas chromatography with mass spectrometric detection and head-space needle trap extraction (two-bed Carbopack X/Carboxen 1000 needle traps) were applied to profile VOCs produced and metabolised by human Simpson Golabi Behmel Syndrome adipocytes. In total, sixteen compounds were identified to be related to the metabolism of the cells. Four sulphur compounds (carbon disulphide, dimethyl sulphide, ethyl methyl sulphide and dimethyl disulphide), three heterocyclic compounds (2-ethylfuran, 2-methyl-5-(methyl-thio)-furan, and 2-pentylfuran), two ketones (acetone and 2-pentanone), two hydrocarbons (isoprene and n-heptane) and one ester (ethyl acetate) were produced, and four aldehydes (2-methyl-propanal, butanal, pentanal and hexanal) were found to be consumed by the cells of interest. This study presents the first profile of VOCs formed by human adipocytes, which may reflect the activity of the adipose tissue enzymes and provide evidence of their active role in metabolic regulation. Our data also suggest that a previously reported increase of isoprene and sulphur compounds in diabetic patients may be explained by their production by adipocytes. Moreover, the unique features of this profile, including a high emission of dimethyl sulphide and the production of furan-containing VOCs, increase our knowledge about metabolism in adipose tissue and provide diagnostic potential for future applications.
Product ion distributions resulting from the primary reactions of H3O+ with nine D-labeled volatile organic compounds and the subsequent sequential reactions with H2O have been determined using a Proton Transfer Reaction Time of Flight Mass Spectrometer (PTR-TOF 8000 (IONICON Analytik GmbH)) at various reduced electric field (E/N) values ranging from 80 up to 150 Td and for two different absolute humidity levels of air sample < 0.1% and 5%. The specific D-labeled compounds used in this study are acetone-d6, toluene-d8, benzene-d6, ethanol-d (C2H5OD), ethanol-d2 (CH3CD2OH), ethanol-d6, 2-propanol-d8, 2-propanol-d3 (CD3CH(OH)CH3), and isoprene-d5 (CH2CHC(CD2)CD3). With the exception of the two 2-propanol compounds, non-dissociative proton transfer is the dominant primary reaction pathway. For 2-propanol-d8 and 2-propanol-d3 the major primary reaction channel involved is dissociative proton transfer. However, unlike their undeuterated counterparts, the primary product ions undergo subsequent deuterium/hydrogen isotope exchange reactions with the ever present water in the drift tube, the extent of which of course depends on the humidity within that tube. This exchange leads to the generation of various isotopologue product ions, the product ion branching percentages of which are also
dependent on the humidity in the drift tube. This results in complex mass spectra and the distribution of product ions leads to issues of reduced sensitivity and accuracy. However, the effect of D/H exchange considerably varies between the compounds under study. In the case of acetone-d6 it is very weak (<1%), because the exchange process is not facile when the deuterium is in the methyl functional group. In comparison, the H3O+/ benzene-d6 (C6D6) reaction and sequential reactions with water result in the production of the isotopologue ions C6Dn(H7-n)+ (where n = 0–6). Changing the value of E/N and/or the humidity in the drift tube considerably affects the amount of the isotope exchange reactions and hence the resulting sequential product ion distributions. An important conclusion of the findings from this work is that care must be taken in the choice of an exogenous deuterated compound for use in breath pharmacokinetic studies using proton transfer reaction mass spectrometry; otherwise the resulting D/H exchange processes impose interpretative problems.
© 2018 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license
(http://creativecommons.org/licenses/by/4.0/).